Functionalized Polyphosphoester via Living Ring-opening Polymerization and Photochemical Thiol-ene Click Reaction

doi:10.1007/s40242-019-8309-0

Chemical Research in Chinese Universities ›› 2019, Vol. 35 ›› Issue (2): 340-344.doi: 10.1007/s40242-019-8309-0

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Functionalized Polyphosphoester via Living Ring-opening Polymerization and Photochemical Thiol-ene Click Reaction

WANG Ying^1,2, WANG Qiliao^2,3, HOU Liman², ZHOU Mingdong¹, DONG Dewen², ZHANG Ning²

1. School of Chemistry and Materials Science, Liaoning Shihua University, Fushun 113001, P. R, China;
2. CAS Key Laboratory of High-performance Synthetic Rubber and Its Composite Materials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China;
3. University of Science and Technology of China, Hefei 230026, P. R. China

Received:2018-09-25 Revised:2018-12-16 Online:2019-04-01 Published:2019-04-30
Contact: ZHOU Mingdong, ZHANG Ning E-mail:mingdong.zhou@lnpu.edu.cn;ning.zhang@ciac.ac.cn
Supported by:
Supported by the Fund of the CAS Key Laboratory of High-performance Synthetic Rubber and Its Composite Materials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences(No.KLSR1602) and the Fund of the Department of Science and Technology of Jilin Province, China(No.20180101170JC).

Abstract

Abstract: Poly(ethylene phosphonate) was synthesized via the living ring-opening polymerization of cyclic phosphonate monomer catalyzed by organocatalyst. The pendant vinyl functionalities were employed to perform the photochemical click reactions with thiols. We demonstrated that both small thiol molecules and macromolecular thiols could be efficiently coupled into the PPE side chains, enabling the rapid and efficient functionalization of polyphosphoesters(PPE).

Key words: Cyclic phosphonate, Ring-opening polymerization, Thiol-ene click reaction, Post modification

WANG Ying, WANG Qiliao, HOU Liman, ZHOU Mingdong, DONG Dewen, ZHANG Ning. Functionalized Polyphosphoester via Living Ring-opening Polymerization and Photochemical Thiol-ene Click Reaction[J]. Chemical Research in Chinese Universities, 2019, 35(2): 340-344.

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Functionalized Polyphosphoester via Living Ring-opening Polymerization and Photochemical Thiol-ene Click Reaction

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