Intense Near- and Mid-infrared Absorbing Films of Electrochemically Crosslinked Multinuclear Metallodithiolene Complex Polymers

doi:10.1007/s40242-015-5309-6

Chemical Research in Chinese Universities ›› 2016, Vol. 32 ›› Issue (2): 296-301.doi: 10.1007/s40242-015-5309-6

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Intense Near- and Mid-infrared Absorbing Films of Electrochemically Crosslinked Multinuclear Metallodithiolene Complex Polymers

LIU Bo^1,2, QIAO Wenqiang¹, WANG Zhi Yuan^1,3

1. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China;
2. University of Chinese Academy of Sciences, Beijing 100049, P. R. China;
3. Department of Chemistry, Carleton University, Ontario K1S 5B6, Canada

Received:2015-07-30 Revised:2015-10-19 Online:2016-04-01 Published:2015-11-02
Contact: QIAO Wenqiang E-mail:wqqiao@ciac.ac.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21134005, 21474105) and the Project of the Natural Science and Engineering Research Council of Canada.

Abstract

Abstract:

Novel multinuclear metallodithiolene complexes [(Cbz)₂-BTT-Pd(dppf)]₂Ni[6b, Cbz=carbazole, BTT=benzene-1,2,4,5-tetrathiotate, dppf=1,1'-bis(diphenylphosphino) ferrocene] and polymer [(Cbz)₂-BTT-Ni]_n·[(Et)3(PhCH2)N]_x(7b) with the carbazole pendent groups were synthesized and characterized. The thin films of crosslinked polymers P6b and P7b were prepared by electrochemical polymerization of compounds 6b and 7b, respectively. These films show intense and broad absorption in the near- and mid-infrared spectral regions(P6b: 1000-1600 nm, λ_max=1297 nm; P7b: 800 nm-8 μm, λ_max=3.9 μm) and are potentially useful as infrared optical materials.

Key words: Metallodithiolene, Carbazole, Electrochemical polymerization, Infrared absorption

LIU Bo, QIAO Wenqiang, WANG Zhi Yuan. Intense Near- and Mid-infrared Absorbing Films of Electrochemically Crosslinked Multinuclear Metallodithiolene Complex Polymers[J]. Chemical Research in Chinese Universities, 2016, 32(2): 296-301.

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Intense Near- and Mid-infrared Absorbing Films of Electrochemically Crosslinked Multinuclear Metallodithiolene Complex Polymers

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