Synthesis and Crystal Structure of Lanthanum Nitrate with Methyl-2-pyridyl Ketone Benzoyl Hydrazone

Chemical Research in Chinese Universities ›› 2003, Vol. 19 ›› Issue (4): 434-436.

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Synthesis and Crystal Structure of Lanthanum Nitrate with Methyl-2-pyridyl Ketone Benzoyl Hydrazone

TAI Xi-shi¹, YIN Xian-hong^1,2, LIU Debo¹, TAN Min-yu¹, YU Kai-bei³

1. College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, P. R. China;
2. Department of Chemistry, Guangxi University for Nationalities, Nanning 530006, P. R. China;
3. Analysis and Measurement Center, Chengdu Branch of Chinese Academy of Sciences, Chengdu 610041, P. R. China

Received:2002-09-17 Online:2003-12-24 Published:2011-08-06
Supported by:
Supported by the National Natural Science Foundation of China(No.29871014) and the Foundation of Doctor by Lanzhou University.

Abstract

Abstract: A novel La complex with methyl-2-pyridyl ketone benzoyl hydrazone has been synthesized and determined by single crystal X-ray diffraction. The crystal is monoclinic with space group C2/c, a=1.7081(3) nm, b=1.5660(3) nm, c=1.3512(3) nm, α=90.00°, β=94.39(1)°, γ=90.00°, V=3.6037(12) nm³, Z=4. The complex is a ten-coordinated one with a lanthanum ion surrounded by a N₄O₆ set. The crystal structure is stabilized by hydrogen bonds between water molecules and NO₃^- anions.

Key words: Synthesis, Lanthanum complex, Methyl-2-pyridyl ketone benzoyl hydrazone, Crystal structure

TAI Xi-shi, YIN Xian-hong, LIU Debo, TAN Min-yu, YU Kai-bei. Synthesis and Crystal Structure of Lanthanum Nitrate with Methyl-2-pyridyl Ketone Benzoyl Hydrazone[J]. Chemical Research in Chinese Universities, 2003, 19(4): 434-436.

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Synthesis and Crystal Structure of Lanthanum Nitrate with Methyl-2-pyridyl Ketone Benzoyl Hydrazone

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