Synthesis and Biological Activity of New Pyrethroid Acid Oxime-esters Containing Pyrazole Ring

Chemical Research in Chinese Universities ›› 2003, Vol. 19 ›› Issue (3): 297-301.

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Synthesis and Biological Activity of New Pyrethroid Acid Oxime-esters Containing Pyrazole Ring

MA Jun-an, HUANG Run-qiu, FENG Lei, SONG Jian, QIU De-wen

Institute and State Key Laboratory of Elemento-organic Chemistry, Nankai University, Tianjin 300071, P. R. China

Received:2002-04-16 Online:2003-08-24 Published:2011-08-06
Supported by:
Supported by the National Natural Science Foundation of China(No.29832050).

Abstract

Abstract: A series of compounds containing oxime-ester linkage and pyrazole ring(in place of the ester linkage and the alcohol moiety in pyrethroid ester) was designed and synthesized. The structures of all the compounds prepared were confirmed by ¹H NMR and MS spectroscopy as well as elemental analyses. The bioassay data of those compounds against tobacco mosaic virus(TMV), cucumber mosaic virus(CMV), potato virus X(PVX) and potato virus Y(PVY) were presented. Among them compound 6i was found to possess significant plant antiviral activities. But all the compounds showed low insecticidal and acaricidal activities.

Key words: Pyrethroid, Oxime-ester, Synthesis, Pyrazole, Plant antiviral activity

MA Jun-an, HUANG Run-qiu, FENG Lei, SONG Jian, QIU De-wen. Synthesis and Biological Activity of New Pyrethroid Acid Oxime-esters Containing Pyrazole Ring[J]. Chemical Research in Chinese Universities, 2003, 19(3): 297-301.

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Synthesis and Biological Activity of New Pyrethroid Acid Oxime-esters Containing Pyrazole Ring

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