Hydrothermal Synthesis and Crystal Structure of [(CH3CH2)4N]4[(La12(OH)12MoO29)], A Novel Cluster Compound with a MoO5 Hexahedron Center Surrounded by La-O Octahedron

Chemical Research in Chinese Universities ›› 2003, Vol. 19 ›› Issue (2): 132-134.

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Hydrothermal Synthesis and Crystal Structure of [(CH₃CH₂)₄N]₄[(La₁₂(OH)₁₂MoO₂₉)], A Novel Cluster Compound with a MoO₅ Hexahedron Center Surrounded by La-O Octahedron

ZHANG Hong¹, WANG Xiu-li¹, LI Yang-guang¹, DUANG Li-ying¹, LAN Yang¹, WANG Li¹, WANG En-bo¹, HU Chang-wen¹

1. Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun 130024, P. R. China;
2. Tonghua Higher Vocational Education Institute, Tonghua 134001, P. R. China

Received:2002-02-06 Online:2003-04-24 Published:2011-08-06
Supported by:
Supported by the National Natural Science Foundation of China(No.20171010).

Abstract

Abstract: A novel compound [(CH₃CH₂)₄N]₄[(La₁₂(OH)₁₂MoO₂₉)] was synthesized by hydrothermal reaction. The single crystal X-ray diffraction shows that the compound crystallized in the monoclinic space group C2/c; a=2.5729(4) nm, b=1.4318(1) nm, c=2.1217(4) nm, β=111.56(1)°, V=6.8235(7) nm³, Z=4, R=0.0751. The basic building blocks of the crystal structure included one MoO₅ hexahedron and twelve LaO₆ octahedra which shared a common edge to form a [(La₁₂(OH)₁₂MoO₂₉)]^4- unit. These units were held together by the [(CH₃CH₂)₄N]⁺ ions.

Key words: Hydrothermal synthesis, Layer, Lanthanum, Triclinic system

ZHANG Hong, WANG Xiu-li, LI Yang-guang, DUANG Li-ying, LAN Yang, WANG Li, WANG En-bo, HU Chang-wen . Hydrothermal Synthesis and Crystal Structure of [(CH₃CH₂)₄N]₄[(La₁₂(OH)₁₂MoO₂₉)], A Novel Cluster Compound with a MoO₅ Hexahedron Center Surrounded by La-O Octahedron[J]. Chemical Research in Chinese Universities, 2003, 19(2): 132-134.

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Hydrothermal Synthesis and Crystal Structure of [(CH₃CH₂)₄N]₄[(La₁₂(OH)₁₂MoO₂₉)], A Novel Cluster Compound with a MoO₅ Hexahedron Center Surrounded by La-O Octahedron

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