Hydrothermal Synthesis and Structure of [CH3NH3]2[(VⅣO)2(VⅤO4)2]:A New Layered Mixed-valence Vanadium Oxide Incorporated with Organic Cations

Chemical Research in Chinese Universities ›› 2002, Vol. 18 ›› Issue (3): 252-254.

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Hydrothermal Synthesis and Structure of [CH₃NH₃]₂[(V^ⅣO)₂(V^ⅤO₄)₂]:A New Layered Mixed-valence Vanadium Oxide Incorporated with Organic Cations

ZHANG Hong¹, LI Yang-guang¹, LAN Yang¹, WANG Xiu-li¹, Duan Li-ying¹, WANG En-bo¹, HU Chang-wen¹, YAO Yuan-gen², CHEN Jiu-tong², QIN Ye-yan²

1. Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun 130024, P. R. China;
2. Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China

Received:2002-02-06 Online:2002-08-24 Published:2011-08-04
Supported by:
Supported by the National Natural Science Foundation of China(No.20171010).

Abstract

Abstract: A new layered mixed-valence vanadium oxide, [CH₃NH₃]₂[(V^ⅣO)₂(V^ⅤO₄)₂], which contains interlamellar organic cations was prepared under hydrothermal conditions and its single-crystal structure was determined. It crystallizes in a triclinic system with space group P1, a=0.625 59(8) nm, b=0.639 84(9) nm, c=0.747 19(10) nm, α=78.718(2)°, β=80.099(2)°, γ=77.100(2). The compound contains mixed-valence V⁴⁺/V⁵⁺ vanadium oxide layers constructed from VO₄ tetrahedra, pairs of edge-sharing VO₅ square pyramid and methylamine with protonated organic amines occupying the interlayer space.

Key words: Hydrothermal synthesis, Layer, Vanadium oxide, Mixed-valence, Structure

ZHANG Hong, LI Yang-guang, LAN Yang, WANG Xiu-li, Duan Li-ying, WANG En-bo, HU Chang-wen, YAO Yuan-gen, CHEN Jiu-tong, QIN Ye-yan. Hydrothermal Synthesis and Structure of [CH₃NH₃]₂[(V^ⅣO)₂(V^ⅤO₄)₂]:A New Layered Mixed-valence Vanadium Oxide Incorporated with Organic Cations[J]. Chemical Research in Chinese Universities, 2002, 18(3): 252-254.

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Hydrothermal Synthesis and Structure of [CH₃NH₃]₂[(V^ⅣO)₂(V^ⅤO₄)₂]:A New Layered Mixed-valence Vanadium Oxide Incorporated with Organic Cations

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