Syntheses and Structural Characterizations of η5-2,4-Cyclopentadien-1-yl Di-carbonyliron Heteronuclear Bi-Metallic Complexes

Chemical Research in Chinese Universities ›› 2001, Vol. 17 ›› Issue (1): 63-68.

• Articles • Previous Articles Next Articles

Syntheses and Structural Characterizations of η⁵-2,4-Cyclopentadien-1-yl Di-carbonyliron Heteronuclear Bi-Metallic Complexes

GAO Jin-sheng¹, MA Zhong-guo¹, YE Ling², BU Wei-ming², MA Dong-sheng¹, YU Chang-hua², GE Yue¹, FAN Yu-guo²

1. Department of Chemistry, Heilongjiang University, Harbin 150080, P. R. China;
2. Key Laboratory of Supramolecular Structure and Spectroscopy, Jilin University, Changchun 130023, P. R. China

Received:2000-03-14 Online:2001-01-24 Published:2011-08-04

Abstract

Abstract: The novel complexes, Cp(CO)₂FeTiCp₂Cl(1) and Cp(CO)₂FeSn(CH₂CMe₂Ph)₃(2), were synthesized and characterized by means of elemental analyses and IR spectra, Cp(CO)₂FeSn·(CH₂CMe₂Ph)₃ was additionally characterized by X-ray crystal structure analysis. The results of the elemental analyses are in good agreement with the theoretical values. The IR spectra show the existence of η⁵-2,4-cyclopentadien-1-yl, carbonyl and methyl groups in the title complexes. The above experimental results show that the M—M'bond exists in Cp(CO)₂FeSn·(CH₂Me₂Ph)₃, while the existence of the M—M'bond in Cp(CO)₂FeTiCp₂Cl is highly possible, too. Both the two complexes are rather stable towards air and moisture, easily soluble in tetrahydrofuran and toluene, while their solubilities are greatly different in n-hexane.

Key words: Metal metal bond, Heteronuclear bimetallic complex, Synthesis, Characterization, Crystal structure

GAO Jin-sheng, MA Zhong-guo, YE Ling, BU Wei-ming, MA Dong-sheng, YU Chang-hua, GE Yue, FAN Yu-guo . Syntheses and Structural Characterizations of η⁵-2,4-Cyclopentadien-1-yl Di-carbonyliron Heteronuclear Bi-Metallic Complexes[J]. Chemical Research in Chinese Universities, 2001, 17(1): 63-68.

[1]	LIU Zailun, SUN Like, ZHANG Qitao, TENG Zhenyuan, SUN Hongli, SU Chenliang. TiO₂-supported Single-atom Catalysts: Synthesis, Structure, and Application [J]. Chemical Research in Chinese Universities, 2022, 38(5): 1123-1138.
[2]	FAN Kui, SUN Yining, XU Pengcheng, GUO Jian, LI Zhenhua, SHAO Mingfei. Single-atom Catalysts Based on Layered Double Hydroxides [J]. Chemical Research in Chinese Universities, 2022, 38(5): 1185-1196.
[3]	JI Yuancheng, XU Jiayun, SUN Hongcheng, and LIU Junqiu. Artificial Photosynthesis(AP): from Molecular Catalysts to Heterogeneous Materials [J]. Chemical Research in Chinese Universities, 2022, 38(3): 688-697.
[4]	CHEN Juan, WANG Jiajia, CHEN Chongan and YANG Guoyu. Two New Borates Built by Different Types of {B₉} Cluster Units [J]. Chemical Research in Chinese Universities, 2022, 38(3): 744-749.
[5]	Mohammad Javad TAGHIZADEH, Maryam Saleh MOHAMMADNIA, Masoumeh GHALKHANI, Esmail SOHOULI. Improved Method for the Total Synthesis of Azaperone and Investigation of Its Electrochemical Behavior in Aqueous Solution [J]. Chemical Research in Chinese Universities, 2022, 38(2): 546-551.
[6]	WANG Lu, WANG Dong. Two-dimensional Covalent Organic Frameworks: Tessellation by Synthetic Art [J]. Chemical Research in Chinese Universities, 2022, 38(2): 265-274.
[7]	HUA Chen, YI Pin, LIU Wencong, WANG Mengfan, NIU Zheng, LANG Jianping. Coordination Polymers with Bipyridyl Diene and Triene Ligands: Synthesis, Structures and Luminescent Properties [J]. Chemical Research in Chinese Universities, 2022, 38(1): 209-216.
[8]	WANG Zelin, LIU Guihao, SHEN Tianyang, TAN Ling, ZHAO Yufei, SONG Yu-Fei. Remote Synthesis of Layered Double Hydroxide Nanosheets Through the Automatic Chemical Robot [J]. Chemical Research in Chinese Universities, 2022, 38(1): 217-222.
[9]	ZHANG Xiaosi, YANG Miao, TIAN Peng, LIU Zhongmin. Progress in Seed-assisted Synthesis of (Silico) Aluminophosphate Molecular Sieves [J]. Chemical Research in Chinese Universities, 2022, 38(1): 1-8.
[10]	LUAN Huimin, WU Qinming, ZHANG Jian, WANG Yeqing, MENG Xiangju, XIAO Feng-Shou. Sustainable Synthesis of Core-Shell Structured ZSM-5@Silicalite-1 Zeolite [J]. Chemical Research in Chinese Universities, 2022, 38(1): 136-140.
[11]	SUN Xiao-Shuang, QIN Dan, LI Xu-Yan, YANG Guo-Yu. A New Tubular Borate Built by[B₁₄O₂₄(OH) ₆]^12- Cluster Units [J]. Chemical Research in Chinese Universities, 2022, 38(1): 123-127.
[12]	FANG Yuan, HEYDARI Zahra, LIU Chenghao, ZHANG Nianyue, CUCCIA Louis A., IVASENKO Oleksandr, PEREPICHKA Dmitrii F.. Glaser Coupling of Substituted Anthracene Diynes on a Non-metallic Surface at the Vapor-Solid Interface [J]. Chemical Research in Chinese Universities, 2021, 37(5): 1143-1148.
[13]	ZHAO Lei, YANG Ge, GUO Hailing, WANG Chunzheng, WANG Lijuan, Svetlana MINTOVA. Effect of Sodium Concentration on the Synthesis of Faujasite by Two-step Synthesis Procedure [J]. Chemical Research in Chinese Universities, 2021, 37(5): 1137-1142.
[14]	ZHANG Ling, FU Yihong, DING Yue, MENG Jiao, WANG Zhenchao, WANG Peiyi. Antibacterial Activity of Novel 18β-Glycyrrhetinic Hydrazide or Amide Derivatives [J]. Chemical Research in Chinese Universities, 2021, 37(3): 662-667.
[15]	DONG Xin, CHEN Xi, ZHOU Zhaohui. Efficient Synthesis of p-Hydroxyphenyl Ethanol from Hydrogenation of Methyl p-Hydroxyphenylacetate with CNTs-promoted Cu-Zr Catalyst [J]. Chemical Research in Chinese Universities, 2021, 37(3): 745-750.

Syntheses and Structural Characterizations of η⁵-2,4-Cyclopentadien-1-yl Di-carbonyliron Heteronuclear Bi-Metallic Complexes

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments