Synthesis and Characterization of Zinc Succinate, Zn(C4H4O4)

Chemical Research in Chinese Universities ›› 2001, Vol. 17 ›› Issue (1): 20-25.

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Synthesis and Characterization of Zinc Succinate, Zn(C₄H₄O₄)

ZHENG Yue-qing, PET ERS Karl, von SCH NERING Hans Georg

1. Institute for Solid State Chemistry, Ningbo University, Ningbo 315211, P. R. China;
2. Max-Planck Institute für Festkrperforschung, D-70569 Stuttgart, Germany

Received:1999-08-05 Online:2001-01-24 Published:2011-08-04
Supported by:
Supported by the Zhejiang Provincial NSF(RC99034)and Special Fund of Ning bo Scientific Technical Commission and Ningbo Educational Committee.

Abstract

Abstract: Zn(C₄H₄O₄) prepared by dissolving 0.483 g (1.41 mol) of Zn₃(OH)₄CO₃·H₂O and 0.5 g (4.23 mol) of C₄H₆O₄ in 50 mL of H₂O followed by slow evaporation at room temperature crystallizes in the monoclinic space group C2 with the cell parameters a=0.757　9(1) nm, b=0.597　6(1) nm, c=0.626　5(1) nm, β=108.45(1)°, V=0.269　17(7) nm³, D_x=2.239g/cm³, Z=2 and the final R(F_o)=0.039 and wR(F_O²)=0.088 for 396 reflections ［F_O²≥2σ(F_O²)］. In the crystal structure unit, each Zn is tetrahedrally coordinated by four O atoms from four (C₄H₄O₄)^2- anions, each of which, in turn, bridges four Zn atoms to build up a 3D³_∞［Zn(C₄H₄O₄)_4/4］ network. The thermal analyses indicate that Zn(C₄H₄O₄) is stable below 420 ℃.

Key words: Synthesis, Zinc succinate, Crystal structure, Thermal decomposition

ZHENG Yue-qing, PET ERS Karl, von SCH NERING Hans Georg. Synthesis and Characterization of Zinc Succinate, Zn(C₄H₄O₄)[J]. Chemical Research in Chinese Universities, 2001, 17(1): 20-25.

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Synthesis and Characterization of Zinc Succinate, Zn(C₄H₄O₄)

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