Synthesis of Liquid Crystalline Polymers with Side Chains

Chemical Research in Chinese Universities ›› 1993, Vol. 9 ›› Issue (2): 143-147.

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Synthesis of Liquid Crystalline Polymers with Side Chains

YANG Chun-cai¹, ZHAO Dong-hui¹, TANG Xin-yi¹, FENG Gui-zen²

1. Department of Chemistry, Jilin University, Changchun, 130023;
2. The Epidemic Preventive Station of Jilin Province, Changchun, 130023)ZHAO Xiao-guang ZHOU En-le (Changchun Institute of Applied Chemistry, Academia Sinica, Changchun, 130022

Received:1992-04-24 Online:1993-04-24 Published:2011-08-17

Abstract

Abstract: The present paper covers the synthesis and characterization of several intermediate products, monomer, and polymers. 3-{ 2-[ 4-(4-Nitrophenylazo) phenoxy] ethyloxycarbonyl} propanoyloxy (2-hydroxy) propyl acrylate (4) was prepared by the ring-opening reaction of glycidyl acrylate with the monoester of succinic acid (3). The polymers (5) with different molecular weights were prepared by the free-radical polymerization. The polymers (5) had liquid crystalline behavior without decomposition as revealed by DSC, optical microscope.

Key words: Synthesis, Side chain liquid crystalline, Free radical polymerization, Polymer

YANG Chun-cai, ZHAO Dong-hui, TANG Xin-yi, FENG Gui-zen. Synthesis of Liquid Crystalline Polymers with Side Chains[J]. Chemical Research in Chinese Universities, 1993, 9(2): 143-147.

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Synthesis of Liquid Crystalline Polymers with Side Chains

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