Chemical Research in Chinese Universities ›› 1990, Vol. 6 ›› Issue (3): 210-217.

• Articles • Previous Articles     Next Articles

Investigation on Oxidation-Reduction Properties of Some Fe-S and Mo-Fe-S Clusters

Zhang Hengbin, Xu Jiqing, Zhang Hongjie   

  1. Department of Chemistry, Jilin University, Changchun
  • Received:1989-08-11 Online:1990-08-24 Published:2011-09-09

Abstract: Oxidation-reduction properties of some Fe-Sand Mo-Fe-Sclusters have been studied by cyclic voltammetric measurement. It is indicated that there are some factors which affect the oxidation- reduction properties of clusters, of which are charge density of metal atom in cluster core, electron effect of ligands, charge and geometric configurations of the reactant particle, etc.

Key words: Cluster, Redox, Fe-S and Mo-Fe-S clusters