Multifunctional Sodium Gluconate Electrolyte Additive Enabling Highly Reversible Zn Anodes

doi:10.1007/s40242-024-4110-9

Abstract

Abstract: Sodium gluconate (SG) is reported as an electrolyte additive for rechargeable aqueous zinc batteries. The SG addition is proposed to modulate the nucleation overpotential and plating behaviors of Zn by forming a shielding buffer layer because of the adsorption priority and large steric hindrance effect, which contributes to limited rampant Zn²⁺diffusion and mitigated hydrogen evolution and corrosion. With the introduction of 30 mmol/L SG in 2 mol/L ZnSO₄ electrolyte, the Zn anode harvests a reversible cycling of 1200 h at 5 mA/cm² and a high average Coulombic efficiency of Zn plating/stripping (99.6%). Full cells coupling Zn anode with V₂O₅·1.6H₂O or polyaniline cathode far surpass the SG additive-free batteries in terms of cycle stability and rate capability. This work provides an inspiration for design of a high-effective and low-cost electrolyte additive towards Zn-based energy storage devices.

Key words: Electrolyte additive, Zn anode, Sodium gluconate, Adsorption, Zn dendrite

ZHAO Kang, ZHAO Jianan, YU Meng, LIU Fangming, DONG Yang, WANG Shiwen, CHENG Fangyi. Multifunctional Sodium Gluconate Electrolyte Additive Enabling Highly Reversible Zn Anodes[J]. Chemical Research in Chinese Universities, 2024, 40(4): 722-729.

References

[1] Zhao R., Wang H., Du H., Yang Y., Gao Z., Qie L., Huang Y., Nat. Commun., 2022, 13, 3252.
[2] Wang L., Zhang B., Zhou W., Zhao Z., Xin Liu, Zhao R., Sun Z., Li H., Wang X., Zhang T., Jin H., Li W., Elzatahry A., Hassan Y., Fan H. J., Zhao D., Chao D., J. Am. Chem. Soc., 2024, 146, 6199.
[3] Liu M., Yuan W., Ma G., Qiu K., Nie X., Liu Y., Shen S., Zhang N., Angew. Chem. Int. Ed., 2023, 62, e202304444.
[4] Wang Q., Kaushik S., Xiao X., Xu Q., Chem. Soc. Rev., 2023, 52, 6139.
[5] Li H., Zhao R., Zhou W., Wang L., Li W., Zhao D., Chao D., JACS Au, 2023, 3, 2107.
[6] Wu J., Yuan C., Li T., Yuan Z., Zhang H., Li X., J. Am. Chem. Soc., 2021, 143, 13135.
[7] Guo X., Zhang Z., Li J., Luo N., Chai G.-L., Miller T. S., Lai F., Shearing P., Brett D. J. L., Han D., Weng Z., He G., Parkin I. P., ACS Energy Lett., 2021, 6, 395.
[8] Wu W., Deng Y., Chen G., Chinese Chem. Lett., 2023, 34, 108424.
[9] Di S., Nie X., Ma G., Yuan W., Wang Y., Liu Y., Shen S., Zhang N., Energy Storage Mater., 2021, 43, 375.
[10] Liu X., Fang Y., Liang P., Xu J., Xing B., Zhu K., Liu Y., Zhang J., Yi J., Chinese Chem. Lett., 2021, 32, 2899.
[11] Wang L., Fan G., Liu J., Zhang L., Yu M., Yan Z., Cheng F., Chinese Chem. Lett., 2021, 32, 1095.
[12] Wang T., Tang Y., Yu M., Lu B., Zhang X., Zhou J., Adv. Funct. Mater., 2023, 33, 2306101.
[13] Zhang L., Xiao J., Xiao X., Xin W., Geng Y., Yan Z., Zhu Z., eScience, 2024, 4, 100205.
[14] Li J., Rohrens D., Dalfollo G., Wu X., Lu Z., Gao Q., Han B., Sun R., Zhou C., Wang J., Cai Z., Nano Mater. Sci., 2023, DOI: 10.1016/j.nanoms.2023.11.004.
[15] Huang J.-Q., Guo X., Lin X., Zhu Y., Zhang B., Research, 2019, 2019, 2635310.
[16] Xiong P., Lin C., Wei Y., Kim J.-H., Jang G., Dai K., Zeng L., Huang S., Kwon S. J., Lee S.-Y., Park H. S., ACS Energy Lett., 2023, 8, 2718.
[17] Zhao K., Fan G., Liu J., Liu F., Li J., Zhou X., Ni Y., Yu M., Zhang Y.-M., Su H., Liu Q., Cheng F., J. Am. Chem. Soc., 2022, 144, 11129.
[18] Wang C., Hou J., Gan Y., Xie L., He Y., Hu Q., Liu S., Jun S. C., J. Mater. Chem. A, 2023, 11, 8057.
[19] Zhang W., Zhang C., Wang H., Wang H., Chem. Res. Chinese Universities, 2023, 39, 1037.
[20] Wang D., Lv D., Liu H., Zhang S., Wang C., Wang C., Yang J., Qian Y., Angew. Chem. Int. Ed., 2022, 61, e202212839.
[21] Zheng L., Li H., Wang X., Chen Z., Hu C., Wang K., Gao G., Passerini S., Zhang H., ACS Energy Lett., 2023, 8, 2086.
[22] Huang C., Zhao X., Hao Y., Yang Y., Qian Y., Chang G., Zhang Y., Tang Q., Hu A., Chen X., Energy Environ. Sci., 2023, 16, 1721.
[23] Li T. C., Lin C., Luo M., Wang P., Li D.-S., Li S., Zhou J., Yang H. Y., ACS Energy Lett., 2023, 8, 3258.
[24] Shi X., Wang J., Yang F., Liu X., Yu Y., Lu X., Adv. Funct. Mater., 2023, 33, 2211917.
[25] Hu Z., Zhang F., Zhou A., Hu X., Yan Q., Liu Y., Arshad F., Li Z., Chen R., Wu F., Li L., Nano-Micro Lett., 2023, 15, 171.
[26] Luo X., Zhou M., Luo Z., Shi T., Li L., Xie X., Sun Y., Cao X., Long M., Liang S., Fang G., Energy Storage Mater., 2023, 57, 628.
[27] Hou Z., Gao Y., Zhou R., Zhang B., Adv. Funct. Mater., 2022, 32, 2107584.
[28] Kim M., Lee J., Kim Y., Park Y., Kim H., Choi J. W., J. Am. Chem. Soc., 2023, 145, 15776.
[29] Sun P., Ma L., Zhou W., Qiu M., Wang Z., Chao D., Mai W., Angew. Chem. Int. Ed., 2021, 60, 18247.
[30] Zhao K., Sheng J., Luo N., Ding J., Luo H., Jia X., Wang S, Fang S., J. Colloid Interf. Sci., 2024, 664, 816.
[31] Wang J., Qiu H., Zhao Z., Zhang Y., Zhao J., Ma Y., Li J., Xing M., Li G., Cui G., Chem. Res. Chinese Universities, 2021, 37, 328.
[32] Wan J., Wang R., Liu Z., Zhang L., Liang F., Zhou T., Zhang S., Zhang L., Lu Q., Zhang C., Guo Z., ACS Nano, 2023, 17, 1610.
[33] Xin T., Zhou R., Xu Q., Yuan X., Zheng Z., Li Y., Zhang Q., Liu J., Chem. Eng. J., 2023, 452, 139572.
[34] Wang N., Chen X., Wan H., Zhang B., Guan K., Yao J., Ji J., Li J., Gan Y., Lv L., Tao L., Ma G., Wang H., Zhang J., Wang H., Adv. Funct. Mater., 2023, 33, 2300795.
[35] Zhong Y., Cheng Z., Zhang H., Li J., Liu D., Liao Y., Meng J., Shen Y., Huang Y., Nano Energy, 2022, 98, 107220.
[36] Yan M., Xu C., Sun Y., Pan H., Li H., Nano Energy, 2021, 82, 105739.
[37] Zhao K., Liu F., Fan G., Liu J., Yu M., Yan Z., Zhang N., Cheng F., ACS Appl. Mater. Interfaces, 2021, 13, 47650.
[38] Zhao Z., Zhao J., Hu Z., Li J., Li J., Zhang Y., Wang C., Cui G., Energy Environ. Sci., 2019, 12, 1938.
[39] Chen Y., Ma D., Ouyang K., Yang M., Shen S., Wang Y., Mi H., Sun L., He G., Zhang P., Nano-Micro Lett., 2022, 14, 154.
[40] Jin Y., Han K. S., Shao Y., Sushko M. L., Xiao J., Pan H., Liu J., Adv. Funct. Mater., 2020, 30, 2003932.
[41] Yin J., Liu H., Li P., Feng X., Wang M., Huang C., Li M., Su Y., Xiao B., Cheng Y., Xu X., Energy Storage Mater., 2023, 59, 102800.
[42] Qin R., Wang Y., Zhang M., Wang Y., Ding S., Song A., Yi H., Yang L., Song Y., Cui Y., Liu J., Wang Z., Li S., Zhao Q., Pan F., Nano Energy, 2021, 80, 105478.
[43] Sun C., Wu C., Gu X., Wang C., Wang Q., Nano-Micro Lett., 2021, 3, 89.
[44] Cao Z., Zhu X., Xu D., Dong P., Chee M. O. L., Li X., Zhu K., Ye M., Shen J., Energy Storage Mater., 2021, 36, 132.