Ionic Liquid-assisted Formation of Lanthanide Metal-organic Framework Nano/Microrods for Superefficient Removal of Congo Red

doi:10.1007/s40242-015-5237-5

Chemical Research in Chinese Universities ›› 2015, Vol. 31 ›› Issue (6): 899-903.doi: 10.1007/s40242-015-5237-5

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Ionic Liquid-assisted Formation of Lanthanide Metal-organic Framework Nano/Microrods for Superefficient Removal of Congo Red

XIAO Yi¹, CHEN Fang¹, ZHU Xixi¹, QIN Hongling¹, HUANG Hongmei¹, ZHANG Youyu¹, YIN Dulin¹, HE Xiaoxiao², WANG Kemin²

1. Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research, Ministry of Education, College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, P. R. China;
2. State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry andChemical Engineering, College of Biology, Hunan University, Changsha 410082, P. R. China

Received:2015-06-15 Revised:2015-08-15 Online:2015-11-01 Published:2015-09-02
Contact: HUANG Hongmei, WANG Kemin E-mail:huanghongmei@hunnu.edu.cn;kmwang@hnu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.21475042), the Scientific Research Fund of Hunan Provincial Education Department, China(No.12B077), the Open Fund Project of State Key Laboratory of Chemo/Biosensing and Chemometrics in Hunan University, China(No.201103) and the Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province, China.

Abstract

Abstract:

New lanthanide metal-organic framework(MOF) nano/microrods, [C₄mim]Cl-Eu-MOF, [C₈mim]Cl-Eu- MOF and [C₁₂mim]Cl-Eu-MOF, were conveniently synthesized via an ionic liquid-assisted hydrothermal method and characterized by means of powder X-ray diffraction(XRD), Fourier transform infrared spectroscopy(FTIR), thermogravimetric analysis(TG) and transmission electron microscopy(TEM). The obtained nano/microrods with low surface areas were efficient for the removal of Congo red(CR) from aqueous solutions. Under the optimum conditions, [C₄mim]Cl-Eu-MOF with a specific surface area of 5.1 m²/g exhibited an ultrahigh adsorption capacity of 2606 mg/g toward CR. Notably, the adsorption efficiency of [C₄mim]Cl-Eu-MOF for CR via nano/microscale stacking can be directly demonstrated by TEM. In-depth understanding of CR removal by [C₄mim]Cl-Eu-MOF nano/microrods was also supported by FTIR, Raman spectroscopy and zeta potential analyses.

Key words: Lanthanide metal-organic framework, Nano/microrod, Ionic liquid, Congo red, Adsorption

XIAO Yi, CHEN Fang, ZHU Xixi, QIN Hongling, HUANG Hongmei, ZHANG Youyu, YIN Dulin, HE Xiaoxiao, WANG Kemin. Ionic Liquid-assisted Formation of Lanthanide Metal-organic Framework Nano/Microrods for Superefficient Removal of Congo Red[J]. Chemical Research in Chinese Universities, 2015, 31(6): 899-903.

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Ionic Liquid-assisted Formation of Lanthanide Metal-organic Framework Nano/Microrods for Superefficient Removal of Congo Red

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