Hyper-crosslinked Porous Polymer Based on Bulk Rigid Monomer for Gas and Dye Absorptions

doi:10.1007/s40242-017-6467-5

Chemical Research in Chinese Universities ›› 2017, Vol. 33 ›› Issue (3): 479-483.doi: 10.1007/s40242-017-6467-5

• Articles • Previous Articles Next Articles

Hyper-crosslinked Porous Polymer Based on Bulk Rigid Monomer for Gas and Dye Absorptions

SHAN Liang, WANG Li, FAN Yong, SHEN Lanlan, WANG Shengyan, XU Jianing

College of Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2016-11-23 Revised:2017-02-10 Online:2017-06-01 Published:2017-04-05
Contact: XU Jianing,E-mail:xujn@jlu.edu.cn E-mail:xujn@jlu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21171065, 21201077).

Abstract

Abstract:

Using the rigid 3,3-bis(4-hydroxyphenyl)-2-(4-tritylphenyl)isoindolin-1-one with polar functional groups as a building block and formaldehyde dimethyl acetal(FDA) as crossinglinker, a new hyper-crosslinked polymer (HCP) was synthesized via Friedel-Crafts alkylation reaction promoted by anhydrous FeCl₃. The synthesized HCP is insoluble in boiled water and common organic solvents. Moreover, it shows a good CO₂ capture capacity even if its surface area is not very high, and the absolute CO₂ uptake capacity of it is 3.05 mmol/g. This can be attributed to the introduction of polar hydroxyl and lactam groups into the skeleton of the polymer, which provides effective adsorption sites for CO₂. In addition, the synthesized HCP also exhibits good adsorption capacity for organic dyes in water, especially for crystal violet.

Key words: Hyper-crosslinked polymer, CO₂ adsorption, Dye adsorption

SHAN Liang, WANG Li, FAN Yong, SHEN Lanlan, WANG Shengyan, XU Jianing. Hyper-crosslinked Porous Polymer Based on Bulk Rigid Monomer for Gas and Dye Absorptions[J]. Chemical Research in Chinese Universities, 2017, 33(3): 479-483.

References

[1] Chen Q., Luo M., Hammershoj P., Zhou D., Han Y., Laursen B. W., Yan C. G., Han B. H., J. Am. Chem. Soc., 2012, 134, 6084
[2] Luo Y. L., Li B. Y., Wang W., Wu K. B., Tan B., Adv. Mater., 2012, 24, 5703
[3] Li B. Y., Guan Z. H., Wang W., Yang X. J., Hu J. L., Tan B., Li T., Adv. Mater., 2012, 24, 3390
[4] Gu C., Huang N., Gao J., Xu F., Xu Y. H., Jiang D. L., Angew. Chem., Int. Ed., 2014, 53, 4850
[5] Fang Q. R., Wang J. H., Gu S., Kaspar R. B., Zhuang Z. B., Zheng J., Guo H. X., Qiu S. L., Yan Y. S., J. Am. Chem. Soc., 2015, 137, 8352
[6] Cote A. P., Benin A. I., Ockwig N. W., O'Keeffe M., Matzger A. J., Yaghi O. M., Science, 2005, 310, 1166
[7] Feng X., Ding X. S., Jiang D. L., Chem. Soc. Rev., 2012, 41, 6010
[8] Ding S. Y., Wang W., Chem. Soc. Rev., 2013, 42, 548
[9] Wood C. D., Tan B., Trewin A., Niu H. J., Bradshaw D., Rosseinsky M. J., Khimyak Y. Z., Campbell N. L., Kirk R., Stocker E., Cooper A. I., Chem. Mater., 2007, 19, 2034
[10] McKeown N. B., Budd P. M., Macromolecules, 2010, 43, 5163
[11] Jiang J. X., Su F., Trewin A., Wood C. D., Campbell N. L., Niu H. J., Dickinson C., Ganin A. Y., Rosseinsky M. J., Khimyak Y. Z., Cooper A. I., Angew. Chem. Int. Ed., 2007, 46, 8574
[12] Xu Y. H., Jin S. B., Xu H., Nagai A., Jiang D. L., Chem. Soc. Rev., 2013, 42, 8012
[13] Ben T., Ren H., Ma S. Q., Cao D. P., Lan J. H., Jing X. F., Wang W. C., Xu J., Deng F., Simmons J. M., Qiu S. L., Zhu G. S., Angew. Chem. Int. Ed., 2009, 48, 9457
[14] Luo Y. L., Zhang S. C., Ma Y. X., Wang W., Tan B. E., Polym. Chem., 2013, 4, 1126
[15] Dawson R., Ratvijitvech T., Corker M., Laybourn A., Khimyak Y. Z., Cooper A. I., Adams D. T., Polym. Chem., 2012, 3, 2034
[16] Martin C. F., Stockel E., Clowes R., Adams D. J., Cooper A. I., Pis J. J., Rubiera F., Pevida C., J. Mater. Chem., 2011, 21, 5475
[17] Dawson R., Stevens L. A., Drage T. C., Snape C. E., Smith M. W., Adams D. J., Cooper A. I., J. Am. Chem. Soc., 2012, 134, 10741
[18] Zhang C., Zhu P. C., Tan L. X., Liu J. M., Tan B., Yang X. L., Xu H. B., Macromoecules, 2015, 48, 8509
[19] Li B. Y., Gong R. N., Wang W., Huang X., Zhang W., Li H. M., Hu C. X., Tan B., Macromolecules, 2011, 44, 2410
[20] Yao S. W., Yang X., Yu M., Zhang Y. H., Jiang J. X., J. Mater. Chem. A, 2014, 2, 8054
[21] Dawson R., Stockel E., Holst J. R., Adams D. J., Cooper A. I., Energy Environ. Sci., 2011, 4, 4239
[22] Zheng J. F., Wang J., Zhang S. B., Yuan T., Yang H., J. Power Sources, 2014, 245, 1005
[23] Luo Y. L., Li B. Y., Wang W., Wu K. B., Tan B. E., Adv. Mater., 2012, 24, 5703
[24] Ren H., Ben T., Sun F. X., Guo M. Y., Jing X. F., Ma H. P., Cai K., Qiu S. L., Zhu G. S., J. Mater. Chem., 2011, 21, 10348
[25] Jing X. F., Zou D. L., Cui P., Ren H., Zhu G. S., J. Mater. Chem. A, 2013, 1, 13926
[26] Weber J., Antonietti M., Thomas A., Macromolecules, 2008, 41, 2880
[27] Dawson R., Cooper A. I., Adams D. J., Polym. Int., 2013, 62, 345
[28] Furukawa H., Yaghi O. M., J. Am. Chem. Soc., 2009, 131, 8875
[29] Wang S. B., Boyjoo Y., Choueib A., Zhu Z. H., Water Res., 2005, 39, 129
[30] Shen D. Z., Fan J. X., Zhou W. Z., Gao B. Y., Yue Q. Y., Kang Q., J. Hazard. Mater., 2009, 172, 99
[31] Crini G., Bioresour. Technol., 2006, 97, 1061

Hyper-crosslinked Porous Polymer Based on Bulk Rigid Monomer for Gas and Dye Absorptions

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 4

Recommended Articles

Metrics

Comments

[1]	SONG Jialong, WANG Zitao, LIU Yaozu, TUO Chao, WANG Yujie, FANG Qianrong, and QIU Shilun. A Three-dimensional Covalent Organic Framework for CO₂ Uptake and Dyes Adsorption [J]. Chemical Research in Chinese Universities, 2022, 38(3): 834-837.
[2]	LI Ying, PAN Bo, MIAO Hongyan, XU Humin, LIU Xuefeng, SHI Gang. Single and Binary Dye Adsorption of Methylene Blue and Methyl Orange in Alcohol Aqueous Solution via Rice Husk Based Activated Carbon: Kinetics and Equilibrium Studies [J]. Chemical Research in Chinese Universities, 2020, 36(6): 1272-1278.
[3]	KANG Dawei, XIE Jingjing, LIU Yingying, MA Jianfang. Four Coordination Polymers Assembled with a New Biscarboxyl-functionalized Schiff Base Ligand [J]. Chemical Research in Chinese Universities, 2018, 34(5): 839-843.
[4]	WANG Wei, YUAN Ye, SUN Fuxing, ZHAO Ming, REN Hao, ZHU Guangshan. Novel Porous Aromatic Framework with Excellent Separation Capability of CO₂ in N₂ or CH₄ [J]. Chemical Research in Chinese Universities, 2014, 30(6): 1018-1021.