A Two-dimensional Dual-pore Covalent Organic Framework for Efficient Iodine Capture

doi:10.1007/s40242-022-2057-2

Abstract

Abstract: Effectively capturing volatile radioiodine generated during the nuclear fission process is considered to be a safe way to the utilization of nuclear power. Here we report a new two-dimensional covalent organic framework(2D COF), ETTA-PyTTA-COF, as a highly efficient iodine adsorbent, which is constructed through the condensation reaction between 4,4’,4’’,4’’’-(ethene-1,1,2,2-tetrayl)-tetrabenzaldehyde(ETTA) and 1,3,6,8-tetrakis(4-aminophenyl)pyrene(PyTTA). The ETTA-PyTTA-COF possesses a permanent 1D channel porous structure with a high Brunauer-Emmet-Teller(BET) surface area of 1519 m²/g and excellent chemical and thermal stability. It shows ultrahigh iodine adsorption capability, which can reach up to 4.6 g/g in vapor owing to its high BET surface area, large π-conjugated structure and plenty of imine groups in the skeleton of the COF as effective iodine sorption sites.

Key words: Covalent organic framework, Iodine capture, Porous material, Adsorbent, Nuclear energy

WEN Zhongliang, WANG Shenglin, FU Siyao, QIAN Jiaying, YAN Qianqian, XU Huanjun, ZUO Kaiming, SU Xiaofang, ZENG Chaoyuan, GAO Yanan. A Two-dimensional Dual-pore Covalent Organic Framework for Efficient Iodine Capture[J]. Chemical Research in Chinese Universities, 2022, 38(2): 472-477.

References

[1] Dorina F. S., Mark A. R., Karena W. C., Peter J. C., Jeffery A. G., Paul S. C., Tina M. N., J. Am. Chem. Soc., 2011, 133, 12398.
[2] Jenna A. B., Carlos O. M., Michel S., Andrew M. R., Neil J. H., Malachi S.,ACS Omega, 2020, 5(9), 4588.
[3] Lee W. E., Ojovan M. I., Stennett M. C., Hyatt N. C., Adv. Appl. Ceram., 2006, 105, 3.
[4] Karena W. C., Peter J. C., Tina M. N., J. Am. Chem. Soc., 2010, 132, 8897.
[5] Subrahmanyam K. S., Sarma D., Malliakas C. D., Polychronopoulou K., Riley B. J., Pierce D. A., Chun J., Kanatzidis M. G., Chem. Mater., 2015, 27, 2619.
[6] Sun H. X., La P. Q., Zhu Z. Q., Liang W. D., Yang B. P., Li A., J. Mater. Sci., 2015, 50, 7326.
[7] Wang H., William P. L., Li J., Chem. Soc. Rev., 2018,47, 4729.
[8] Thaer A., Bassem A., J. Nucl. Mater., 2017, 493, 6.
[9] Sava D. F., Chapman K. W., Rodriguez M. A., Greathouse J. A., Crozier P. S., Zhao H., Chupas P. J., Nenoff T. M., Chem. Mater., 2013, 25, 2591.
[10] Feng X., Ding X. S., Jiang D. L., Chem. Soc. Rev., 2012, 41, 6010.
[11] Geng K. Y., Arumugam V., Xu H. J., Gao Y. A., Jiang D. L., Prog. Polym. Sci., 2020, 108, 101288.
[12] Xiang Z. H., Cao D. P., J. Mater. Chem. A, 2013,1, 2691.
[13] Ding S. Y., Wang W., Chem. Soc. Rev., 2013, 42, 548.
[14] Peter J., Gándara W. F., Yaghi O. M., Acc. Chem. Res., 2015, 48, 3053.
[15] Tian Y. Y., Zhu G. S., Chem. Rev., 2020, 120, 8934.
[16] Li Y. S., Chen W. B., Xing G. L., Jiang D. L., Chen L., Chem. Soc. Rev., 2020,49, 2868.
[17] Li H., Chen F. Q., Guan X. Y., Li J. L., Li C. Y., Tang B., Valtchev V., Yan Y. S., Qiu S. L., Fang Q. R., J. Am. Chem. Soc., 2021, 143, 2654.
[18] Hu H., Yan Q. Q., Ge R. L., Gao Y. A., Chinese J. Catal., 2018, 39, 1167.
[19] Furukawa H., Yaghi O. M., J. Am. Chem. Soc., 2009, 131, 8875.
[20] Wei H., Chai S. Z., Hu N. T., Yang Z., Wei L. M., Wang L., Chem. Commun., 2015, 51, 12178.
[21] Rabbani M. G., Sekizkardes A. K., Kahveci Z., Reich T. E., Ding R., El-Kaderi H. M., Chem. Eur. J., 2013, 19, 3324.
[22] Zhao S., Dong B., Ge R. L., Wang C., Song X. D., Ma W., Wang Y., Hao C., Guo X. W., Gao Y. A., RSC Adv., 2016,6, 38774.
[23] Wei P. F., Qi M. Z., Wang Z. P., Ding S. Y., Yu W., Liu Q., Wang L. K., Wang H. Z., An W. K., Wang W. J. Am. Chem. Soc., 2018, 140, 4623.
[24] Xu H. S., Ding S. Y., An W. K., Wu H., Wang W., J. Am. Chem. Soc., 2016, 138, 11489.
[25] Shinde D. B., Kandambeth S., Pachfule P., Kumar R. R., Banerjee R., Chem. Commun., 2015, 51, 310.
[26] Kandambeth S., Venkatesh V., Shinde D. B., Kumari S., Halder A., Verma S., Banerjee R., Nat. Commun., 2015, 6, 6786.
[27] Alahakoon S. B., Thompson C. M., Occhialini G., Smaldone R. A., ChemSusChem., 2017, 10, 2116.
[28] Zhang Y., Riduan S. N., Wang J., Chem. Eur. J., 2017,23, 16419.
[29] Lin C. Y., Zhang D., Zhao Z., Xia Z., Adv. Mater., 2018, 30, 1703646.
[30] Wan S., Guo J., Kim J., Ihee H., Jiang D. L., Angew. Chem., Int. Ed., 2009, 48, 5439.
[31] Ding H. M., Li Y. H., Hu H., Sun Y. M., Wang J. G., Wang C. X., Wang C., Zhang G. X., Wang B. H., Xu W., Zhang D. Q., Chem. Eur. J., 2014, 20, 14614.
[32] Feng X., Chen L., Honsho Y., Saengsawang O., Liu L. L., Wang L., Saeki A., Irle S., Seki S., Dong Y. B., Jiang D. L., Adv. Mater., 2012, 24, 3026.
[33] Wang C, Wang Y., Ge R. L., Song X. D., Xing X. Y., Jiang Q. K., Lu H., Hao C., Guo X. W., Gao Y. A., Jiang D. L., Chem. Eur. J., 2018, 24, 585.
[34] Zhu Y., Qi Y, Guo X. H., Zhang M. C., Jia Z. M., Xia C. Q., Liu N., Bai C. Y., Ma L. J., Wang Q., J. Mater. Chem. A, 2021,9, 16961.
[35] Zhai L. P., Sun S. Z., Chen P. J., Zhang Y. W., Sun Q. K., Xu Q., Wu Y. J., Nie R. M., Li Z. P., Mi L. W., Mater. Chem. Front., 2021, 5, 5463.
[36] Li Y., Li X. J., Li J. F., Liu W, Cheng G. E., Ke H. Z., Micropor. Mesopor. Mater., 2021, 325, 111351..
[37] Yin Z. J., Xu S. Q., Zhan T. G., Qi Q. Y., Wu Z. Q., Zhao X., Chem. Commun., 2017, 53, 1.
[38] Song S., Shi Y., Liu Y, Liu F. Q., ACS Appl. Mater. Interfaces, 2021, 13, 10513.
[39] Li Y., Chen W. B., Hao W. J., Li Y. S., Chen L., ACS Appl. Nano Mater., 2018, 1, 4756.
[40] Tong D. Y., Zhao Y. L., Chen Z. G., Wang Y. Q., Jia Z. Q., Nie X. M., Xiao S. T., Phys. Chem. Chem. Phys., 2021, 23, 25365.
[41] Wang P., Xu Q., Li Z. P., Jiang W. M., Jiang Q. H., Jiang D. L., Adv. Mater., 2018, 30, 1801991.
[42] Song S., Shi Y., Liu N., Liu F. Q., RSC Adv., 2021, 11, 10512.
[43] Qu H., Wang Y., Li Z. H., Wang X. C., Fang H. X., Tian Z. Q., Cao. X. Y., J. Am. Chem. Soc., 2017, 139, 18142.
[44] Jin S. B., Sakurai T., Kowalczyk T., Dalapati S., Xu F., Wei H., Chen X., Gao J., Seki S., Irle S., Jiang D. L., Chem. Eur. J., 2014, 20, 14608.
[45] Chen R., Hu T. L., Zhang W., He C. Y., Li Y. Q., Micropor. Mesopor. Mater., 2021, 312, 110739.
[46] He L., Chen L., Dong X., Zhang S., Zhang M., Dai X., Liu X., Lin P., Li K., Chen C., Pan T., Ma F., Chen J., Yuan M., Zhang Y., Chen L., Zhou R., Han Y., Chai Z., Wang S., Chem, 2021, 7, 699.
[47] Zeng M. H., Wang Q. X., Tan Y. X., Hu S., Zhao H. X., Long L. S., Kurmoo M., J. Am. Chem. Soc. 2010, 132, 2561.
[48] Yin Z., Wang Q. X., Zeng M. H., J. Am. Chem. Soc. 2012, 134, 4857.