PVA/PEG Hybrid Hydrogels Prepared by Freeze-thawing and High Energy Electron Beam Irradiation

doi:10.1007/s40242-017-7107-9

Chemical Research in Chinese Universities ›› 2017, Vol. 33 ›› Issue (6): 995-999.doi: 10.1007/s40242-017-7107-9

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PVA/PEG Hybrid Hydrogels Prepared by Freeze-thawing and High Energy Electron Beam Irradiation

ZHAO Chunming, LU Xueting, HU Qianqian, LIU Shuai, GUAN Shuang

School of Chemistry and Life Science, Advanced Institute of Materials Science, Changchun University of Technology, Changchun 130012, P. R. China

Received:2017-03-22 Revised:2017-07-25 Online:2017-12-01 Published:2017-08-07
Contact: GUAN Shuang,E-mail:guanshuang@ccut.edu.cn E-mail:guanshuang@ccut.edu.cn
Supported by:
Supported by the Project of the Department of Depointment and Reform Commission of Jilin Province, China(No.2017c054-1).

Abstract

Abstract: In this paper, poly(vinyl alcohol)(PVA) and PVA/poly(ethylene glycol)(PEG) hybrid hydrogels were synthesized by freeze-thawing or freeze-thawing followed by high energy electron beam irradiation. The influence of PEG molecular weight, mass ratios of PVA to PEG, thawing temperature and number of freeze-thawing(FT) cycles on the mechanical strength of PVA/PEG hydrogel was investigated. Also, the thermal behaviors were examined by differential scanning calorimetry(DSC) and the microstructures were observed with scanning electron microscopy(SEM). The results suggest that the addition of PEG improves the mechanical strength of PVA hydrogel and the irradiation reduces both the strength of PVA/PEG hydrogel slightly and the degree of crystallinity. The improved properties suggest that PVA/PEG hydrogel can be a good candidate for the application in the biomedical.

Key words: Poly (vinyl alcohol), Poly (ethylene glycol), High energy beam irradiation, Freeze-thawing, Hydrogel

ZHAO Chunming, LU Xueting, HU Qianqian, LIU Shuai, GUAN Shuang. PVA/PEG Hybrid Hydrogels Prepared by Freeze-thawing and High Energy Electron Beam Irradiation[J]. Chemical Research in Chinese Universities, 2017, 33(6): 995-999.

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PVA/PEG Hybrid Hydrogels Prepared by Freeze-thawing and High Energy Electron Beam Irradiation

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