Fabrication of CeO2/rGO Nanocomposites with Oxidase-like Activity and Their Application in Colorimetric Sensing of Ascorbic Acid

doi:10.1007/s40242-017-7002-4

Abstract

Abstract:

Nanomaterial-based artificial enzymes(nanozymes) have shown great potential for application in colorimetric sensing. In this paper, the nanocomposites of CeO₂ and reduced graphene oxide(rGO) were fabricated via a one-pot hydrothermal process, in which CeO₂ nanoparticles were well anchored on the surface of rGO. The prepared CeO₂/rGO nanocomposites exhibited excellent catalytic activity for the oxidation of 3,3',5,5'-tetramethylbenzidine(TMB) in the presence of O₂. Compared with the individual CeO₂ nanoparticles, the nanocomposites had a higher affinity and adsorptivity towards the substrate TMB, which was due to the combination of rGO. In addition, based on the oxidase-like activity of CeO₂/rGO nanocomposites, a facile and sensitive colormetric sensor for ascorbic acid(AA) was investigated. The detection limit of AA was low(0.15 μmol/L) and the linear detection range was between 0.5 μmol/L and 40 μmol/L. Furthermore, the colorimetric system was used for the detection of AA in medicine and food analysis, such as tablets, beverage and milk powder.

Key words: Nanozyme, Oxidase-like, Colorimetric, Ascorbic acid

WANG Jiangning, SU Ping, LI Di, WANG Ting, YANG Yi. Fabrication of CeO₂/rGO Nanocomposites with Oxidase-like Activity and Their Application in Colorimetric Sensing of Ascorbic Acid[J]. Chemical Research in Chinese Universities, 2017, 33(4): 540-545.

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Fabrication of CeO₂/rGO Nanocomposites with Oxidase-like Activity and Their Application in Colorimetric Sensing of Ascorbic Acid

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