A Highly Selective Fluorescent Chemosensor for Cu2+

doi:10.1007/s40242-015-4403-0

Chemical Research in Chinese Universities ›› 2015, Vol. 31 ›› Issue (3): 347-351.doi: 10.1007/s40242-015-4403-0

• Articles • Previous Articles Next Articles

A Highly Selective Fluorescent Chemosensor for Cu²⁺

GUAN Jie, ZHANG Peng, WEI Taibao, LIN Qi, YAO Hong, ZHANG Youming

Key Laboratory of Eco-environment-related Polymer Materials, Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, P. R. China

Received:2014-10-23 Revised:2015-01-26 Online:2015-06-01 Published:2015-02-12
Contact: ZHANG Youming E-mail:zhangyouming@nwnu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21064006, 21262032, 21161018).

Abstract

Abstract:

A new Zn²⁺ probe L2-Zn(L2=naphthofuran carbonylhydrazone derivant) was synthesized as a fluorescence chemosensor for Cu²⁺, by which Cu²⁺ ion could be detected with high selectivity and sensitivity in a wide pH range via a displacement “turn-off” signaling strategy. Whereas the coordination between Zn²⁺ and L2 resulted in a considerable enhancement of typical luminescence of a naphthalofuran group in complex L2-Zn, the addition of Cu²⁺ ion led to a dramatic decrease in the emission intensity of probe L2-Zn at about 503 nm(excitation at 423 nm). The competitive fluorescent experiments showed that other metal ions, such as Hg²⁺, Fe³⁺, Ag⁺, Ca²⁺, Co²⁺, Ni²⁺, Cd²⁺, Pb²⁺, Zn²⁺, Cr³⁺ and Mg²⁺ could not impact the detection of Cu²⁺. The detection limit of the novel probe L2-Zn for Cu²⁺ ion was as low as 2.3×10^-7 mol/L, which is far lower than the guideline value of 1.6×10^-5 mol/L of the United States Environmental Protection Agency.

Key words: Znic complex, Fluorescent switch, Copper ion, Turn-off signal

GUAN Jie, ZHANG Peng, WEI Taibao, LIN Qi, YAO Hong, ZHANG Youming. A Highly Selective Fluorescent Chemosensor for Cu²⁺[J]. Chemical Research in Chinese Universities, 2015, 31(3): 347-351.

References

[1] Shiraishi Y., Tanaka K., Hirai T., ACS Appl. Mater. Interfaces, 2013, 8, 3456
[2] Kelly B., Rozas I., Tetrahedron Lett., 2013, 54, 3982
[3] Shao X. L., Gu H., Wang Z., Chai X. L., Tian Y., Shi G. Y., Anal. Chem., 2013, 85, 418
[4] Wang C. Y., Wong K. M., Inorg. Chem., 2013, 52, 13432
[5] Wang M. L., Meng G. W., Huang Q., Qian Y. W., Environ. Sci. Technol., 2012, 46, 367
[6] Lin Y., Lin W. Y., Chen B., Xie Y. A., Org. Lett., 2012, 14, 432
[7] Fan J. L., Zhan P., Hu M. M., Org. Lett., 2013, 12, 492
[8] Waggoner D. J., Bart T. B., Gitlin J. D., Neurobiol. Dis., 1999, 6, 221
[9] Vulpe C., Levinson B., Whitney S. P., Gitschier J., Nat. Genet., 1993, 3, 7
[10] Bull P. C., Thomas G. R., Rommens J. M., Forbes J. R., Cox D. W., Nat. Genet., 1993, 5, 327
[11] Valentine J. S., Hart B. G., Winkler J. R., Proc. Natl. Acad. Sci. USA, 2008, 130, 6898
[12] Han B. X., Wu F. Y., Chem. J. Chinese. Universities, 2013, 34(11), 2483
[13] Meloni G., Faller P., Vasak M., J. Biol. Chem., 2007, 282, 16068
[14] Wei T. B., Li J. J., Lin Q., Yao H., Guo Y., Bai C. B., Xie Y. Q., Zhang Y. M., Chem. J. Chinese. Universities, 2012, 33(11), 2452
[15] Li X. B., Niu Z. G., Chang L. L., Chen M. X., Wang E. J., Chin. Chem. Lett., 2014, 25, 80
[16] Aragay G., Pons J., Merkoçi A., Chem. Rev., 2011, 111, 3433
[17] Quang D. T., Kim J. S., Chem. Rev., 2010, 110, 6280
[18] Formica M., Fusi V., Giorgi L., Micheloni M., Coord. Chem. Rev., 2012, 256, 170
[19] Kim H. N., Guo Z., Zhu W., Yoon J., Tian H., Chem. Soc. Rev., 2011, 40, 79
[20] Yang Y. M., Zhao Q., Feng W., Li F. Y., Chem. Rev., 2013, 113, 192
[21] Vendrell M., Zhai D., Er J. C., Chang Y. T., Chem. Rev., 2012, 112, 4391
[22] Jo J. Y., Lee H. Y., Liu W. J., Olasz A., Chen C. H., Lee D. H., J. Am. Chem. Soc., 2012, 134, 16000
[23] Wang L. H., Jiang S., Zhang Z. J., Zhang H. Y., Liu Y., Chem. J. Chinese. Universities, 2013, 34(9), 2108
[24] Tang L. J., Cai M. J., Huang Z. L., Zhong S. H., Hou Y. J., Bian R. N., Sen. Act. B, 2013, 185, 188
[25] Caballero A., Campos P. J., Rodríguez M. A., Tetrahedron, 2013, 69, 4631
[26] Chawla H. M., Shukla R., Pandey S., Tetrahedron Lett., 2013, 54, 2063
[27] Gupta V. K., Singh A. K., Ganjali M. R., Norouzi P., Faridbod F., Mergu N., Sen. Act. B, 2013, 182, 642
[28] Jang Y. K., Nam U. C., Kwon H. L., Hwang I. H., Kim C., Dye Pigm., 2013, 99, 6
[29] Ge F., Ye H., Luo J. Z., Wang S., Sun Y. J., Zhao B. X., Miao J. Y., Sen. Act. B, 2013, 181, 215
[30] He G. J., Zhao Y. G., He C., Liu Y., Duan C. Y., Inorg. Chem., 2008, 47, 5169
[31] Ye W. P., Wang S. X., Meng X. M., Feng Y., Sheng H. T., Shao Z. L., Zhu M. Z., Guo Q. X., Dye Pigm., 2014, 101, 30
[32] Wei T. B., Li J. J., Bai C. B., Lin Q., Yao H., Xie Y. Q., Zhang Y. M., Sci. Chi. Chem., 2013, 56, 923
[33] Guan J., Zhang P., Wei T. B., Lin Q., Yao H., Zhang Y. M., RSC Adv., 2014, 4, 35797
[34] Nevado J. J. B., Pulgarin J. A. M., Laguna M. A. G., Talanta, 2001, 53, 951
[35] Zhou Y., Li Z. X., Zang S. Q., Zhu Y. Y., Zhang H. Y., Hou H. W., Mak T. C. W., Org. Lett., 2012, 14, 1214

A Highly Selective Fluorescent Chemosensor for Cu²⁺

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 7

Recommended Articles

Metrics

Comments

[1]	CHENG Kai, YANG Wei, WANG Hui, ZHOU Jie, WU Shengji, YU Tianming, PAN Jianbo. Effect of Cu(Ⅱ) on Degradation and Decolorization of Rhodamine B in Subcritical Water [J]. Chemical Research in Chinese Universities, 2017, 33(4): 643-647.
[2]	LIU Xuan, YANG Jiali, TONG Lanyan, ZHANG Qian, LI Xiaowei, CHEN Jida. Preparation of Cu(II)-imprinted Nanofibers from co-Electrospinning PVA and Imprinting Complex [J]. Chemical Research in Chinese Universities, 2015, 31(6): 1062-1065.
[3]	XIAO Yi, LI Sha, HUANG Hong-mei, ZHANG Ye, XUE Zun-zun, TANG Xue-yan, HE Xiao-xiao, WANG Ke-min. Conjugated Polyelectrolyte-Ag⁺ Fluorescent Switch for Biothiol Sensing [J]. Chemical Research in Chinese Universities, 2013, 29(5): 845-849.
[4]	CAO Ben-nan, HU Qin, HUANG Yan, JIA Chun-man, ZHANG Qi. Highly Sensitive and Selective Chemosensor for Cu²⁺ Based on a Schiff Base [J]. Chemical Research in Chinese Universities, 2013, 29(3): 419-423.
[5]	FAN Cai-ling, DAI Xing, YANG Wu-min, WANG Xing-feng and YANG Yun-xu. A Quinoline Derivated Chemosensor for Cu²⁺ Recognition [J]. Chemical Research in Chinese Universities, 2009, 25(5): 620-623.
[6]	ZOU Wen-sheng , SHEN Qian-jin , WANG Yu , JIN Wei-jun . Fluorescent Switch Behavior of 1,2-Bis(4-pyridyl) Ethylene Controlled by pH in Aqueous Solution [J]. Chemical Research in Chinese Universities, 2008, 24(6): 712-716.
[7]	LIU Bin, WANG Hong-mei, LIAO Dai-zheng, YAN Shi-ping, JIANG Zong-hui, WANG Geng-lin, HUANG Xiao-ying . Crystal Structure of the Addition Compound of N,N'-Bi(2-pyridylmethyl)-Oxamide and the Complex of Copper with 1,10-Phenanthroline [J]. Chemical Research in Chinese Universities, 1998, 14(4): 387-390.