Preparation of Cu-MgO Catalysts via Urea-nitrate Combustion Method and Their Catalytic Performance in Vapor Phase Hydrogenation of Furfural

doi:10.1007/s40242-017-6315-7

Chemical Research in Chinese Universities ›› 2017, Vol. 33 ›› Issue (3): 442-446.doi: 10.1007/s40242-017-6315-7

• Articles • Previous Articles Next Articles

Preparation of Cu-MgO Catalysts via Urea-nitrate Combustion Method and Their Catalytic Performance in Vapor Phase Hydrogenation of Furfural

WANG Licheng, BU Tiantong, WANG Zhenlü

Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Jilin University, Changchun 130021, P. R. China

Received:2016-07-25 Revised:2016-08-29 Online:2017-06-01 Published:2016-10-17
Contact: WANG Zhenlü,E-mail:wzl@jlu.edu.cn E-mail:wzl@jlu.edu.cn
Supported by:
Supported by the Jilin Province Science and Technology Research Plan(Key Scientific Research Project), China (No.20150204020GX).

Abstract

Abstract:

A series of Cu-MgO catalysts was prepared via a urea-nitrate combustion method, and their catalytic per-formance was examined in the vapor phase hydrogenation of furfural. Characterization results showed that the amount of urea had important effects on the surface area, Cu dispersion and crystallite size of the catalysts. The Cu-MgO catalyst with a Cu loading of 12.1%(mass fraction) showed higher furfural conversion than the catalyst prepared by coprecipitation. The high activity was attributed to the higher dispersion of Cu on the catalyst surface. These results suggest that the combustion method is an efficient and simple route for the preparation of high activity Cu-MgO catalysts for furfural hydrogenation.

Key words: Furfural, Furfuryl alcohol, Hydrogenation, Cu-MgO catalyst, Combustion

WANG Licheng, BU Tiantong, WANG Zhenlü. Preparation of Cu-MgO Catalysts via Urea-nitrate Combustion Method and Their Catalytic Performance in Vapor Phase Hydrogenation of Furfural[J]. Chemical Research in Chinese Universities, 2017, 33(3): 442-446.

References

[1] Li H., Zhang S., Luo H., Mater. Lett., 2004, 58, 2741
[2] Li H., Luo H., Zhuang L., Dai W., Qiao M., J. Mol. Catal. A:Chem., 2003, 203, 267
[3] Rao S. R., Baker R. T. K., Vannice M., Catal. Lett., 1999, 60, 51
[4] Rao S., Dandekar A., Baker R. T. K., Vannice M. A., J. Catal., 1997, 171, 406
[5] Liu B. J., Lu L. H., Wang B. C., Cai T. X., Katsuyoshi I., Appl. Catal. A:Gen., 1998, 171, 117
[6] Kijenski J., Winiarek P., Paryjczak T., Lewicki A., Mikolajska A., Appl. Catal. A:Gen., 2002, 233, 171
[7] Wu J., Shen Y., Liu C. L., Wang H. B., Geng C. J., Zhang Z. X., Ca-tal. Commun., 2005, 6, 633
[8] Nagaraja B. M., Siva Kumar V., Shasikala V., Padmasri A. H., Sreedhar B., David Raju B., Rama Rao K. S., Catal. Commun., 2003, 4, 287
[9] Zheng J., Zhu W. C., Ma C. X., Hou Y. Z., Zhang W. X., Wang Z. L., Reac. Kinet. Mech. Cat., 2010, 99, 455
[10] Ji D. H., Liu G., Jia M. J., Zhang W. X., Wang G. J., Wu T. H., Wang Z. L., Chem. J. Chinese Universities, 2007, 28(8), 1543
[11] Marinsek M., Zupan K., Maeek J., J. Power Source, 2002, 106, 178
[12] Delimaris D., Ioannides T., Appl. Catal. B:Environ., 2009, 89, 295
[13] Avgouropoulos G., Ioannides T., Appl. Catal. A:Gen., 2003, 244, 155
[14] Purohit R. D., Sharma B. P., Pillai K. T., Tyagic A. K., Mater. Res. Bull., 2001, 36, 2711
[15] Guo X. M., Mao D. S., Lu G. Z., Wang S., Wu G. S., J. Catal., 2010, 271, 178
[16] Tabakva T., Idakiev V., Papavasiliou J., Avgourooulos G., Ioannides T., Catal. Commun., 2007, 8, 101
[17] Nagaraja B. M., Padmasri A. H., Raju B. D., Rao K. S. R., J. Mol. Catal. A:Chem., 2007, 265, 90
[18] Yuan Z. L., Wang J. H., Wang L. N., Xie W. H., Chen P., Hou Z. Y., Zheng X. M., Bioresource Technol., 2010, 101, 7088
[19] Jia M. J., Zhang W. X., Wu T. H., J. Mol. A:Chem., 2002, 185, 151
[20] Chary K.V. R., Sagar G. V., Srikanth C. S., Rao V. V., J. Phys. Chem. B, 2007, 111, 543
[21] Bienholz A., Hofmann H., Claus P., App. Catal. A:Gen., 2011, 391, 153
[22] Avgouropoulos G., Ioannides T., Matralis H., Appl. Catal. B:Environ., 2005, 56, 87
[23] Avgouropoulos G., Ioannides T., Appl. Catal. B:Environ., 2006, 67, 1
[24] Zhang Y. P., Fei J. H., Yu Y. M., Zheng X. M., Energy Convers Manage, 2006, 47, 3360
[25] Chen X. F., Li H. X., Luo H. S., Qiao M. H., Appl. Catal. A:Gen., 2002, 233, 13
[26] Xu W. J., Wang H. F., Liu X. H., Ren J. W., Wang Y. Q., Lu G. Z., Chem. Commun., 2011, 47, 3924
[27] Lei H., Hou Z. Y., Xie J. W., Fuel, 2016, 164, 191

Preparation of Cu-MgO Catalysts via Urea-nitrate Combustion Method and Their Catalytic Performance in Vapor Phase Hydrogenation of Furfural

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	MA Yanfu, WANG Liwei, LIU Jian. Single Atom Catalysts in Liquid Phase Selective Hydrogenations [J]. Chemical Research in Chinese Universities, 2022, 38(5): 1163-1171.
[2]	HUANG Jin, CAI Yichen, YU Yulv, WANG Yuan. Conversion of CO₂ to Multi-carbon Compounds over a CoCO₃ Supported Ru-Pt Catalyst Under Mild Conditions [J]. Chemical Research in Chinese Universities, 2022, 38(1): 223-228.
[3]	DONG Xin, CHEN Xi, ZHOU Zhaohui. Efficient Synthesis of p-Hydroxyphenyl Ethanol from Hydrogenation of Methyl p-Hydroxyphenylacetate with CNTs-promoted Cu-Zr Catalyst [J]. Chemical Research in Chinese Universities, 2021, 37(3): 745-750.
[4]	LIU Yike, LONG Yanhui, TANG Yaqin, GU Zhenhua, LI Kongzhai. Effect of Preparation Method on the Structural Characteristics of NiO-ZrO₂ Oxygen Carriers for Chemical-looping Combustion [J]. Chemical Research in Chinese Universities, 2019, 35(6): 1024-1031.
[5]	LI Hongda, ZHAO Zhen, LI Jiacheng, LI Jianmei, ZHAO Linlin, SUN Jiachen, FAN Xiaoqiang. Synthesis of Pt-SnO_x/TS-1@SBA-16 Composites and Their High Catalytic Performance for Propane Dehydrogenation [J]. Chemical Research in Chinese Universities, 2019, 35(5): 866-873.
[6]	MA Fei, LI Hengli, JIANG Jiuxing. Furfural Reduction via Hydrogen Transfer from Supercritical Methanol [J]. Chemical Research in Chinese Universities, 2019, 35(3): 498-503.
[7]	LIU Junmei, GUO Wanwan, SUN Hao, LI Ruyue, FENG Zhipeng, ZHOU Xuyang, HUANG Jun. Reductive Amination of Carbonyl Compounds with Ammonia and Hydrogenation of Nitriles to Primary Amines with Heterogeneous Cobalt Catalysts [J]. Chemical Research in Chinese Universities, 2019, 35(3): 457-462.
[8]	GAO Biao, LUO Yajun, MIAO Changxi, YUE Yinghong, YANG Weimin, HUA Weiming, GAO Zi. Oxidative Dehydrogenation of 1-Butene to 1,3-Butadiene Using CO₂ over Cr-SiO₂ Catalysts Prepared by Sol-gel Method [J]. Chemical Research in Chinese Universities, 2018, 34(4): 609-615.
[9]	HAN Fuqin, ZHANG Zhe, NIU Na, LI Jian. Preparation and Characterization of SiO₂/Co and C/Co Nanocomposites as Fisher-Tropsch Catalysts for CO₂ Hydrogenation [J]. Chemical Research in Chinese Universities, 2018, 34(4): 635-642.
[10]	LIAO Ziyi, LAN Yang, WANG Kai, LEI Miao, LIAO Yang, MAO Hui, MA Jun, ZHAO Shilin. In situ Growing PtCo Bimetallic Catalyst on Plant Tannin-grafted Collagen Fiber for Catalytic Hydrogenation of Cinnamaldehyde with Desirable Performance [J]. Chemical Research in Chinese Universities, 2018, 34(2): 285-289.
[11]	ZHONG Simei, ZHENG Min, PU Sixu, XING Yanbin, LI Kongzhai, WANG Hua. Thermodynamics on Sulfur Migration in CaSO₄ Oxygen Carrier Reduction by CO [J]. Chemical Research in Chinese Universities, 2017, 33(6): 979-985.
[12]	LIU Shankui, LIU Pengcheng, NIU Ruyue, WANG Shuang, LI Jinping. Facile Synthesis of Mesoporous Co₃O₄ Nanoflowers for Catalytic Combustion of Ventilation Air Methane [J]. Chemical Research in Chinese Universities, 2017, 33(6): 965-970.
[13]	AN Tong, DANG Dan, CHENG Yi. Effect of Reduction and Carburization Pretreatment on Iron Catalyst for Synthesis of Light Olefins from CO Hydrogenation [J]. Chemical Research in Chinese Universities, 2017, 33(4): 672-677.
[14]	MA Jun, LAN Yang, MAO Hui, LIAO Yang, ZHAO Shilin. Preparation of Pt/γ-Al₂O₃-C Heterogeneous Catalyst for Highly Selective Hydrogenation of Cinnamaldehyde Towards Cinnamyl Alcohol [J]. Chemical Research in Chinese Universities, 2017, 33(4): 660-665.
[15]	BEN Shunge, YUAN Fulong, ZHU Yujun. Effect of Zr Addition on Catalytic Performance of Cu-Zn-Al Oxides for CO₂ Hydrogenation to Methanol [J]. Chemical Research in Chinese Universities, 2016, 32(6): 1005-1009.