Facile Synthesis of Mesoporous Co3O4 Nanoflowers for Catalytic Combustion of Ventilation Air Methane

doi:10.1007/s40242-017-7047-4

Chemical Research in Chinese Universities ›› 2017, Vol. 33 ›› Issue (6): 965-970.doi: 10.1007/s40242-017-7047-4

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Facile Synthesis of Mesoporous Co₃O₄ Nanoflowers for Catalytic Combustion of Ventilation Air Methane

LIU Shankui¹, LIU Pengcheng¹, NIU Ruyue¹, WANG Shuang^1,2, LI Jinping¹

1. Research Institute of Special Chemicals, Taiyuan University of Technology, Taiyuan 030024, P. R. China;
2. College of Environmental Science and Engineering, Taiyuan University of Technology, Jinzhong 030600, P. R. China

Received:2017-02-09 Revised:2017-06-12 Online:2017-12-01 Published:2017-09-26
Contact: WANG Shuang,E-mail:wangshuang@tyut.edu.cn;LI Jinping,E-mail:jpli211@hotmail.com E-mail:wangshuang@tyut.edu.cn;jpli211@hotmail.com
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21671147, 51203109) and the Funding of the State Key Laboratory of Coal and Coalbed Methane Co-mining, China.

Abstract

Abstract: Flower-like Co₃O₄ hierarchical microspheres composed of self-assembled porous nanoplates were prepared by employing Pluronic F127 block-copolymer as template. The samples were characterized by powder X-ray diffraction(PXRD), scanning/transmission electron microscopy(SEM/TEM), and nitrogen adsorption-desorption at 77 K. The results show that the catalytic activity of Co₃O₄ nanoflowers for the combustion of ventilation air methane is higher than that of commercial Co₃O₄. The superior catalytic performance of this material can be related to its dominantly exposed {112} crystal planes and higher content of surface Co³⁺.

Key words: Co₃O₄, Nanoflower, Catalytic combustion, Ventilation air methane

LIU Shankui, LIU Pengcheng, NIU Ruyue, WANG Shuang, LI Jinping. Facile Synthesis of Mesoporous Co₃O₄ Nanoflowers for Catalytic Combustion of Ventilation Air Methane[J]. Chemical Research in Chinese Universities, 2017, 33(6): 965-970.

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Facile Synthesis of Mesoporous Co₃O₄ Nanoflowers for Catalytic Combustion of Ventilation Air Methane

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