A Highly Selective and Sensitive Ratiometric Fluorescent Probe for pH Measurement Based on Fluorescence Resonance Energy Transfer

doi:10.1007/s40242-015-5124-0

Chemical Research in Chinese Universities ›› 2015, Vol. 31 ›› Issue (5): 724-729.doi: 10.1007/s40242-015-5124-0

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A Highly Selective and Sensitive Ratiometric Fluorescent Probe for pH Measurement Based on Fluorescence Resonance Energy Transfer

LIANG Fanghui¹, WANG Di², MA Pinyi², WANG Xinghua², SONG Daqian², YU Yong³

1. Department of Pharmacy, Changchun Medical College, Changchun 130031, P. R. China;
2. College of Chemistry, Jilin University, Changchun 130012, P. R. China;
3. College of Instrumentation & Electrical Engineering, Jilin University, Changchun 130061, P. R. China

Received:2015-03-30 Revised:2015-05-06 Online:2015-10-01 Published:2015-05-25
Contact: YU Yong, E-mail: yuyong@jlu.edu.cn E-mail:yuyong@jlu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21405057, 21207047) and the Science and Technology Developing Foundation of Jilin Province, China(No.20125006).

Abstract

Abstract:

Fluorescein-rhodamine 6G(Flu-Rh) was synthesized and used as the fluorescence probe for pH measurement based on fluorescence resonance energy transfer(FRET). In the probe, fluorescein fluorophore and pH-sensitive rhodamine 6G hydrazide were used as FRET donor and acceptor, respectively. The values of acidity constant(pK_a) and fluorescence quantum yield(Φ) of Flu-Rh were 3.71 and 0.72, respectively. The fluorescence efficiency of Flu-Rh remains almost constant when the pH value of the sample solution changed 10 times in a range of 4.78-7.03 continuously. The present probe is simple and easy-to-use for the pH measurement in acidic media.

Key words: Fluorescence resonance energy transfer(FRET), Ratiometric, Fluorescein, Rhodamine 6G, pH

LIANG Fanghui, WANG Di, MA Pinyi, WANG Xinghua, SONG Daqian, YU Yong. A Highly Selective and Sensitive Ratiometric Fluorescent Probe for pH Measurement Based on Fluorescence Resonance Energy Transfer[J]. Chemical Research in Chinese Universities, 2015, 31(5): 724-729.

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A Highly Selective and Sensitive Ratiometric Fluorescent Probe for pH Measurement Based on Fluorescence Resonance Energy Transfer

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