Ruthenium Complex Immobilized on Mesoporous Silica as Recyclable Heterogeneous Catalyst for Visible Light Photocatalysis

doi:10.1007/s40242-014-3367-9

Chemical Research in Chinese Universities ›› 2014, Vol. 30 ›› Issue (2): 310-314.doi: 10.1007/s40242-014-3367-9

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Ruthenium Complex Immobilized on Mesoporous Silica as Recyclable Heterogeneous Catalyst for Visible Light Photocatalysis

HE Hongyan^1,2, LI Wenliang³, XIE Zhigang¹, JING Xiabin¹, HUANG Yubin¹

1. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China;
2. University of Chinese Academy of Sciences, Beijing 100049, P. R. China;
3. School of Life Sciences, Northeast Normal University, Changchun 130024, P. R. China

Received:2013-08-29 Revised:2013-09-22 Online:2014-04-01 Published:2013-10-11
Contact: HUANG Yubin E-mail:ybhuang@ciac.jl.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.51021003, 51273194, 21104075, 21174143).

Abstract

Abstract:

Aldehyde group-functionalized [Ru(bpy)₂L](PF₆)₂ catalyst was prepared and immobilized onto the mesoporous silica nanoparticles to act as a heterogeneous catalyst for the selective oxidation of thioanisole to methyl phenyl sulfoxide under visible light. The heterogeneous catalyst can be easily recovered by simple centrifugation without chemical treatment, exhibiting comparable catalytic efficiency with homogeneous ones and no decrease in catalytic efficiency after at least 5 cycles.

Key words: Heterogeneous catalysis, Visible light photocatalysis, Mesoporous silica nanoparticle, Recovery

HE Hongyan, LI Wenliang, XIE Zhigang, JING Xiabin, HUANG Yubin. Ruthenium Complex Immobilized on Mesoporous Silica as Recyclable Heterogeneous Catalyst for Visible Light Photocatalysis[J]. Chemical Research in Chinese Universities, 2014, 30(2): 310-314.

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Ruthenium Complex Immobilized on Mesoporous Silica as Recyclable Heterogeneous Catalyst for Visible Light Photocatalysis

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