Preparation and Characterization of SiO2-coated 2,4-Hexadiyn-1,6-bis(ethylurea) Microcapsules

doi:10.1007/s40242-014-3344-3

Abstract

Abstract:

A novel kind of time-temperature indicator, SiO₂-coated 2,4-hexadiyn-1,6-bis(ethylurea) microcapsules, has been fabricated by coating SiO₂ on 2,4-hexadiyn-1,6-bis(ethylurea). This kind of microcapsules is a model hydrophilic indicator, its stability is improved. And temperature-induced color change is irreversible even under varying irradiation. The influences of ammonia, tetraethyl orthosilicate(TEOS) and temperature on the product have been investigated. 2,4-Hexadiyn-1,6-bis(ethylurea) and the coated particles have been characterized by means of elemental analysis, mass spectrum, FTIR and Raman spectra and DSC, SEM, TEM and DLS analyses. The results indicate that 2,4-hexadiyn-1,6-bis(ethylurea)/SiO₂ ratios, ammonia concentration and temperature could modulate the monodispersity and size of the microcapsules. The experiments indicate that when the molar ratio of 2,4-hexadiyn- 1,6-bis(ethylurea)/SiO₂/ammonia is 1:3:3.5 and temperature is 40 ℃, the obtained microcapsules are well coated with the best monodispersity. Such sustained-release and hydrophilic microcapsules have very good prospects as a novel time-temperature chromatic indicator.

Key words: 2,4-Hexadiyn-1,6-bis(ethylurea), SiO₂, 2,4-Hexadiyn-1,6-bis(ethylurea)/SiO₂microcapsule

CHENG Huan, ZHU Guangming. Preparation and Characterization of SiO₂-coated 2,4-Hexadiyn-1,6-bis(ethylurea) Microcapsules[J]. Chemical Research in Chinese Universities, 2014, 30(3): 431-436.

References

[1] Zanoni S., Zavanella L., Int. J. Prod. Eco., 2012, 140, 731
[2] Rong A., Akkerman R., Grunow M., Int. J. Pro. Econ., 2011, 131, 421
[3] Ellouze M., Augustin J. C., Int. J. Food Microbiol., 2010, 138, 119
[4] Traiphol N., Rungruangviriya N., Potai R., Traiphol R., J. Colloid Interf. Sci., 2011, 356, 481
[5] Kim J. M., Lee J. S., Choi H., Sohn D., Ahn D. J., Macromolecules, 2005, 38, 9366
[6] Ahn D. J., Lee S., Kim J. M., Adv. Funct. Mater., 2009, 19, 1483
[7] Wacharasindhu S., Montha S., Boonyiseng J., Potisatityuenyong A., Phollookin C., Tumcharern G., Sukwattanasinitt M., Macromolecules, 2010, 43, 716
[8] Wegner G., Die Makromolekulare Chemie., 1972, 154, 35
[9] Hub H. H., Hupfer B., Koch H., Ringsdorf H., Angew. Chem.. Int. Ed. Engl., 1980, 19, 938
[10] Charoenthai N., Pattanatornchai T., Wacharasindhu S., Sukwattanasinitt M., Traiphol R., J. Colloid Interf. Sci., 2011, 360, 565
[11] Pires A. C. S., Soares N. F. F., Silva L. H. M. da, Silva M. C. Hespanhol da, Mageste A. B., Soares R. F., Teixeira A. V. N. C., Andrade N. J., J. Phys. Chem. B, 2010, 114, 13365
[12] Chen X. Q., Yoon J. Y., Dyes Pigments, 2011, 89, 194
[13] Rusli R., Shanmuganathan K., Rowan S. J., Weder C., Eichhorn S. J., Biomacromolecules, 2010, 11, 762
[14] Guo C. X., Boullanger P., Liu T., Jiang L., J. Phys. Chem. B, 2005, 109, 18765
[15] Peng H. S., Sun X. M., Cai F. J., Chen X. L., Zhu Y. C., Liao G. P., Chen D. Y., Li Q. W., Lu Y. F., Zhu Y. T., Jia Q. X., Nat. Nanotechnol., 2009, 4. 738
[16] Yuan Z. Z., Hanks T. W., Polymer, 2008, 49, 5023
[17] Kolusheva S., Shahal T., Jelinek R., J. Am. Chem. Soc., 2000, 122, 776
[18] Lee J., Kim H. J., Kim J., J. Am. Chem. Soc., 2008, 130, 5010
[19] Kwon I. K., Kim J. P., Sim S. J., Biosemsors and Bioelectroniscs, 2010, 26(4), 1548
[20] Su Y. L., Li J. R., Jiang L., Colloid Surface A, 2005, 257, 25
[21] Carpick R. W., Sasaki D. Y., Marcus M. S., Eriksson M. A., Burns A. R., J. Phys-Condens Mat., 2004, 16, 679
[22] Wegner G., Pure & Appl. Chem., 1977, 49. 443
[23] Cao G., Mallouk T. E., J. Solid State Chem., 1991, 94. 59
[24] Menzel H., Horstmanna S., Moweryb M. D., Cai M., Evans C. E., Polymer, 2000, 41, 8113
[25] Schott M., Spagnoli S., Weiser G., Chem. Phys., 2007, 333. 246
[26] Menzel H., Mowery M. D., Cai M., Evans C. E., Macromolecules, 1999, 32, 4343
[27] Graf C., Vossen D. L. J., Imhof A., Van Blaaderen A., Langmuir, 2003, 19. 6693
[28] Jana N. R., Earhart C., Ying J. Y., Chem. Mater., 2007, 19. 5074
[29] Wang S., Yin Q., Li X., Chem. Res. Chinese Universities, 2012, 28(1), 119

Preparation and Characterization of SiO₂-coated 2,4-Hexadiyn-1,6-bis(ethylurea) Microcapsules

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