Synthesis, Crystal Structure and Copper Complex of 1,3-Alternate p-tert-Butylthiacalix[4]arene 2-picolyl Schiff Base

doi:10.1007/s40242-014-3277-x

Abstract

Abstract:

A p-tert-butylthiacalix[4]arene-based polydentated ligand with four Schiff base units on 1,3-alternate position at lower rim has been prepared in three steps, which coordinated to copper ion to form a novel dicopper complex. The structures of the polydentated thiacalixarene ligand and copper complex were fully characterized by spectroscopy and X-ray single crystal diffraction method.

Key words: Calixarene, Thiacalixarene, Schiff base, Pyridine, Copper complex, Crystal structure

HUANG Kun, LIU Kai, YAN Chaoguo. Synthesis, Crystal Structure and Copper Complex of 1,3-Alternate p-tert-Butylthiacalix[4]arene 2-picolyl Schiff Base[J]. Chemical Research in Chinese Universities, 2014, 30(2): 245-249.

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