Effect of Magnetic Carrier NiFe2O4 Nanoparticles on Physicochemical and Catalytic Properties of Magnetically Separable Photocatalyst TiO2/NiFe2O4

doi:10.1007/s40242-013-2143-6

Chemical Research in Chinese Universities ›› 2013, Vol. 29 ›› Issue (1): 121-125.doi: 10.1007/s40242-013-2143-6

Previous Articles Next Articles

Effect of Magnetic Carrier NiFe₂O₄ Nanoparticles on Physicochemical and Catalytic Properties of Magnetically Separable Photocatalyst TiO₂/NiFe₂O₄

XU Shi-hong¹, TAN Dong-dong¹, BI De-fu¹, SHI Peng-hui¹, LU Wei², SHANGGUAN Wen-feng³, MA Chun-yan¹

1. School of Environmental Science and Engineering, Donghua University, Shanghai 201620, P. R. China;
2. Beijing General Municipal Engineering Design & Research Institute, Beijing 100082, P. R. China;
3. Research Center for Combustion and Environment Technology, School of Mechanical and Power Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China

Received:2012-04-09 Revised:2012-06-27 Online:2013-02-01 Published:2013-01-23
Supported by:
Supported by the Shanghai Municipal Natural Science Foundation, China(Nos.11ZR1400400, 11ZR1400800), the Fundamental Research Funds for the Central Universities, China(No.12D11303) and the Shanghai Leading Academic Discipline Project, China(No.B604).

Abstract

Abstract:

A series of magnetically separable photocatalyst TiO₂/NiFe₂O₄(TN) with different mass ratios of NiFe₂O₄ to TiO₂ was prepared by sol-gel method. The X-ray diffraction(XRD), X-ray photoelectron spectroscopy(XPS), transmission electron microscopy(TEM), ultraviolet-visible spectroscopy(UV-Vis), Brunauer-Emmett-Teller(BET) surface analysis and photoluminescence spectroscopy(PL) were used to characterize the photocatalyst TN. The XRD patterns of TN indicate that adulterating a smidgen of NiFe₂O₄ into TiO₂(about 0.1%, mass ratio) can promote the phase transformation of TiO₂, however, when the doped amount of NiFe₂O₄ surpasses 1%, the introduction of NiFe₂O₄ can inhibit the growth of TiO₂ crystal grain and reduce the size of TiO₂ crystal grain. The XPS results of TN indicate that some Fe³⁺ replace Ti⁴⁺ of the TiO₂ lattice forming Fe―O―Ti bonds. The PL analysis of TN shows that the NiFe₂O₄ nanoparticles in photocatalyst TN play the role of the effective recombination centre of the photogenerated electrons and holes, leading to the decrease in photocatalytic activity.

Key words: Photocatalyst, TiO₂, NiFe₂O₄, Magnetical separation

XU Shi-hong, TAN Dong-dong, BI De-fu, SHI Peng-hui, LU Wei, SHANGGUAN Wen-feng, MA Chun-yan. Effect of Magnetic Carrier NiFe₂O₄ Nanoparticles on Physicochemical and Catalytic Properties of Magnetically Separable Photocatalyst TiO₂/NiFe₂O₄[J]. Chemical Research in Chinese Universities, 2013, 29(1): 121-125.

References

[1] Carp O., Huisma C. L., Reller A., Prog. Solid State Chem., 2004, 32(1/2), 33

[2] Mukherjee P. S., Ray A. K., Chem. Eng. Technol., 1999, 22(3), 253

[3] Arslan I., Balcioglu I. A., Bahnemann D. W., Appl. Catal. B: Environ., 2000, 26(3), 193

[4] Chen X. Q., Li F. B., Li X. J., Gu G. B., Soil Environ. Sci., 2001, 10(1), 30

[5] Peng S. C., Xie J. J., Qing C. S., J. Chin. Ceram. Soc., 2006, 34(10), 1208

[6] Shimizu K., Murayama H., Nagai A., Shimada A., Hatamachi T., Kodama T., Kitayama Y., Appl. Catal. B: Environ., 2005, 55(2), 141

[7] Wang L. J., Zhang D. Y., Inorg. Chem. Ind., 2010, 42(6), 15

[8] Horikoshi S., Watanabe N., Onishi H., Hidaka H., Serpone N., Appl. Catal. B: Environ., 2002, 37(2), 117

[9] Beydoun D., Amal R., Low G. K. C., McEvoy S., J. Phys. Chem. B, 2000, 104(18), 4387

[10] Gao Y., Chen B. H., Li H. L., Ma Y. X., Mater. Chem. Phys., 2003, 80(1), 348

[11] Ortega D., Garitaonandia J. S., Barrera-Solano C., Ramirez-Del-Solar M., Blanco E., Dominguez M., J. Non-Cryst. Solids, 2006, 352(26/27), 2801

[12] Chen L. Y., Shen Y. M., Bai J. F., Mater. Lett., 2009, 63(12), 1099

[13] Xu S. H., Shangguan W. F., Yuan J., Chen M. X., Shi J. W., Appl. Catal. B: Environ., 2007, 71(3/4), 177

[14] Xu S. H., Shangguan W. F., Yuan J., Chen M. X., Shi J. W., Chin. J. Chem. Eng., 2007, 15(2), 190

[15] Xu S. H., Shangguan W. F., Yuan J., Chen M. X., Shi J. W., Nanotechnology, 2008, 19(9), 095606

[16] Xu M. W., Bao S. J., Zhang X. G., Mater. Lett., 2005, 59(17), 2194

[17] Kurinobu S., Tsurusaki K., Natui Y., Kimata M., Hasegawa M., Magn. J. Magn. Mater., 2007, 310(2), e1025

[18] Chen F., Xie Y. D., Zhao J. C., Lu G. X., Chemosphere, 2001, 44(5), 1159

[19] Nobile A., Davis M. W., J. Catal., 1989, 116(2), 383

[20] Pal B., Sharon M., Nogami G., Mater. Chem. Phys., 1999, 59(3), 254

[21] Yuan Z. H., Zhang L. D., Chem. J. Chinese Universities, 1999, 20(7), 1007

[22] Li J. X., Xu J. H., Dai W. L., Li H. X., Fan K. N., Appl. Catal. B: Environ., 2009, 85(3/4), 162

[23] Zhu J. F., Chen F., Zhang J. L., Chen H. J., Anpo M., J. Photochem. Photobiol. A: Chem., 2006, 180(1/2), 196

[24] Yuan W., Dai X. M., Ai D. S., Li Q. F., J. Chin. Ceram. Soc., 2002, 30(S1), 31

[25] Balaji S., Selvan R. K., Berchmans L. J., Angappan S., Subramanian K., Augustin C. O., Mater. Sci. Eng. B: Solid State Mater. Adv. Technol., 2005, 119(2), 119

[26] Beydoun D., Amal R., Scott J., Low G. K. C., McEvoy S., Chem. Eng. Technol., 2001, 24(7), 745

[27] Xu S. H., Shangguan W. F., Yuan J., Shi J. W., Chen M. X., Mater. Sci. Eng. B: Solid State Mater. Adv. Technol., 2007, 137(1―3), 108

Effect of Magnetic Carrier NiFe₂O₄ Nanoparticles on Physicochemical and Catalytic Properties of Magnetically Separable Photocatalyst TiO₂/NiFe₂O₄

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	LIU Zailun, SUN Like, ZHANG Qitao, TENG Zhenyuan, SUN Hongli, SU Chenliang. TiO₂-supported Single-atom Catalysts: Synthesis, Structure, and Application [J]. Chemical Research in Chinese Universities, 2022, 38(5): 1123-1138.
[2]	ZHANG Xinyu, TANG Pengpeng, ZHAI Guangyao, LIN Xiu, ZHANG Qiang, CHEN Jiesheng, WEI Xiao. Regulating Phase Junction and Oxygen Vacancies of TiO₂ Nanoarrays for Boosted Photoelectrochemical Water Oxidation [J]. Chemical Research in Chinese Universities, 2022, 38(5): 1292-1300.
[3]	SONG Weiyu, LV Xintong, GAO Yang, WANG Lu. Photocatalytic HER Performance of TiO₂-supported Single Atom Catalyst Based on Electronic Regulation:A DFT Study [J]. Chemical Research in Chinese Universities, 2022, 38(4): 1025-1031.
[4]	SUN Ruixue, TAN Bien. Covalent Triazine Frameworks(CTFs) for Photocatalytic Applications [J]. Chemical Research in Chinese Universities, 2022, 38(2): 310-324.
[5]	ZHENG Gaofeng, PENG Hao, JIANG Jiaxin, KANG Guoyi, LIU Juan, ZHENG Jianyi, LIU Yifang. Surface Functionalization of PEO Nanofibers Using a TiO₂ Suspension as Sheath Fluid in a Modified Coaxial Electrospinning Process [J]. Chemical Research in Chinese Universities, 2021, 37(3): 571-577.
[6]	LI Wenfeng, FANG Xue, LYU Jiahui, WANG Guowen, MA Chun, MA Hongchao. Co₃O₄ Decorated Ti/TiO₂ Nanotubes for Photogenerated Cathodic Protection of 304 Stainless Steel [J]. Chemical Research in Chinese Universities, 2021, 37(3): 704-710.
[7]	YANG Xinzhe, QIN Tingting, ZHANG Xiaoyu, LIU Xiaofei, WANG Zizhun, ZHANG Wei, ZHENG Weitao. Self-crystallized Interlayer Integrating Polysulfide-adsorbed TiO₂/TiO and Highly-electron-conductive TiO for High-stability Lithium-Sulfur Batteries [J]. Chemical Research in Chinese Universities, 2021, 37(2): 259-264.
[8]	CHEN Ting, ZHONG Lei, YANG Zhen, MOU Zhigang, LIU Lei, WANG Yan, SUN Jianhua, LEI Weiwei. Enhanced Visible-light Photocatalytic Activity of g-C₃N₄/Nitrogen-doped Graphene Quantum Dots/TiO₂ Ternary Heterojunctions for Ciprofloxacin Degradation with Narrow Band Gap and High Charge Carrier Mobility [J]. Chemical Research in Chinese Universities, 2020, 36(6): 1083-1090.
[9]	JIANG Wenshuai, ZONG Xupeng, WANG Xiayan, SUN Zaicheng. Transparent Coating with TiO₂ Nanorods for High-performance Photocatalytic Self-cleaning and Environmental Remediation [J]. Chemical Research in Chinese Universities, 2020, 36(6): 1097-1101.
[10]	MENG Zeshuo, ZHOU Bo, XU Jian, LI Yaxin, HU Xiaoying, TIAN Hongwei. Heterostructured Nitrogen and Sulfur co-Doped Black TiO₂/g-C₃N₄ Photocatalyst with Enhanced Photocatalytic Activity [J]. Chemical Research in Chinese Universities, 2020, 36(6): 1045-1052.
[11]	YUAN Huiting, REN Huizhen, LI Minning, LI Zetong, LIU Mingrui, DONG Wenjun, WANG Ge, ZHUANG Tao. Synthesis of N-TiO₂@NH₂-MIL-88(Fe) Core-shell Structure for Efficient Fenton Effect Assisted Methylene Blue Degradation Under Visible Light [J]. Chemical Research in Chinese Universities, 2020, 36(6): 1068-1075.
[12]	HE Yilei, ZHANG Xing, WEI Yanze, CHEN Xiaoyu, WANG Zumin, YU Ranbo. Ti-MOF Derived N-Doped TiO₂ Nanostructure as Visible-light-driven Photocatalyst [J]. Chemical Research in Chinese Universities, 2020, 36(3): 447-452.
[13]	WANG Hui, WANG Jiafeng, ZHANG Lei, YU Qinqin, CHEN Zewen, WU Shengji. A New Strategy for Improving the Efficiency of Low-temperature Selective Catalytic Reduction of NO_x with CH₄ via the Combination of Non-thermal Plasma and Ag₂O/TiO₂ Photocatalyst [J]. Chemical Research in Chinese Universities, 2019, 35(6): 1062-1069.
[14]	WANG Huan, XIAO Liguang, WANG Chao, LIN Bin, LYU Sa, CHU Xuefeng, CHI Yaodan, YANG Xiaotian, WANG Xinyan. Pd/TiO₂ Nanospheres with Three-dimensional Hyperstructure for Enhanced Photodegradation of Organic Dye [J]. Chemical Research in Chinese Universities, 2019, 35(4): 667-673.
[15]	WANG Junlin, YI Yongjie, LI Mengjia, CHANG Yue, ZHA Fei. Graphitic Carbon Nitride Microspheres Supported α-FeO(OH) Hybrids for Visible Light Photodegradation of MO [J]. Chemical Research in Chinese Universities, 2019, 35(2): 319-324.