Co3O4 Decorated Ti/TiO2 Nanotubes for Photogenerated Cathodic Protection of 304 Stainless Steel

doi:10.1007/s40242-020-0226-8

Abstract

Abstract: The Co₃O₄ decorated TiO₂ nanotube arrays(NTAs) coatings are fabricated by the combination of anodization and impregna-ting methods. It is found that the introduction of Co₃O₄ can reduce the diffraction intensity of (101) plane of the TiO₂ and accelerate the separation of photogenerated electron/hole pairs. In addition, the open circuit potential(OCP) and the corrosion potential of 304 stainless steel(304SS) with or without Co₃O₄ decorated TiO₂ NTAs were measured under visible light, which indicated the 304SS coupled with Co₃O₄ decorated TiO₂ NTAs had better anticorrosion performance than that of the 304SS or the 304SS coupled with pure TiO₂ NTAs. The enhancement of the cathodic protection performance of the Co₃O₄ decorated TiO₂ NTAs can be ascribed to the matched energy levels and strong interaction between Co₃O₄ and TiO₂ NTAs, and the improvement of light absorption.

Key words: Photogenerated cathodic protection, Corrosion, Stainless steel, Ti/TiO₂Co₃O₄

LI Wenfeng, FANG Xue, LYU Jiahui, WANG Guowen, MA Chun, MA Hongchao. Co₃O₄ Decorated Ti/TiO₂ Nanotubes for Photogenerated Cathodic Protection of 304 Stainless Steel[J]. Chemical Research in Chinese Universities, 2021, 37(3): 704-710.

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Co₃O₄ Decorated Ti/TiO₂ Nanotubes for Photogenerated Cathodic Protection of 304 Stainless Steel

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