Synthesis of N-TiO2@NH2-MIL-88(Fe) Core-shell Structure for Efficient Fenton Effect Assisted Methylene Blue Degradation Under Visible Light

doi:10.1007/s40242-020-0285-x

Chemical Research in Chinese Universities ›› 2020, Vol. 36 ›› Issue (6): 1068-1075.doi: 10.1007/s40242-020-0285-x

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Synthesis of N-TiO₂@NH₂-MIL-88(Fe) Core-shell Structure for Efficient Fenton Effect Assisted Methylene Blue Degradation Under Visible Light

YUAN Huiting, REN Huizhen, LI Minning, LI Zetong, LIU Mingrui, DONG Wenjun, WANG Ge, ZHUANG Tao

Beijing Advanced Innovation Center for Materials Genome Engineering, Beijing Key Laboratory of Function Materials for Molecule & Structure Construction, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, P. R. China

Received:2020-09-13 Revised:2020-10-13 Online:2020-12-01 Published:2020-12-03
Contact: YUAN Huiting, DONG Wenjun E-mail:wdong@ustb.edu.cn;18610783785@163.com
Supported by:
Supported by the National Natural Science Foundation of China(Nos.52071027, 51872025), the National Key Research and Development Program of China(No.2016YFB0701100), the National Key Research and Development H863 Program of China (No.18H86303ZT0032702) and the Fundamental Research Funds for the Central Universities of China(Nos.FRF-GF-20-03A, FRF-GF-19-006B).

Abstract

Abstract: Core-shell TiO₂-based photocatalysts with specific composition, morphology, and functionality have attracted considerable attention for their excellent degradation properties on organic pollutants via a photocatalytic oxidation process. Herein, a N-TiO₂@NH₂-MIL-88(Fe) core-shell structure was prepared by coating NH₂-MIL-88(Fe) on nitrogen-doped TiO₂(N-TiO₂) nanoparticles. Introduction of heteroatom nitrogen to pure TiO₂ expands the spectral response range, leading to enhanced quantum efficiency of photocatalyst. Furthermore, loading NH₂-MIL-88(Fe) on N-TiO₂ improved the adsorption ability of the nanocomposites due to the porous tunnels of NH₂-MIL-88(Fe). The resulted core-shell N-TiO₂@NH₂-MIL-88(Fe) nanocomposites realized the transfer of photo excited electrons from N-TiO₂ to NH₂-MIL-88(Fe) rapidly, partially reduced Fe³⁺ to Fe²⁺ in NH₂-MIL-88(Fe), and further enhanced the Fenton effect on efficiently degrading methylene blue dye(MB) under visible light(λ ≥ 420 nm) with the assistance of H₂O₂.

Key words: NH₂-MIL-88(Fe), N-TiO₂, Photocatalysis, Fenton effect

YUAN Huiting, REN Huizhen, LI Minning, LI Zetong, LIU Mingrui, DONG Wenjun, WANG Ge, ZHUANG Tao. Synthesis of N-TiO₂@NH₂-MIL-88(Fe) Core-shell Structure for Efficient Fenton Effect Assisted Methylene Blue Degradation Under Visible Light[J]. Chemical Research in Chinese Universities, 2020, 36(6): 1068-1075.

References

[1] Lv F., Ma Y., Xiang P., Shu T., Chen X., J. Alloy. Compd., 2020, 837, 155555
[2] Chen Y., Jiang Y., Wang X., Deng Q., IOP Conference Series:Earth and Environmental Science, 2018, 189(3), 32005
[3] Liao G., Liu Z., Sun B., Liu X., Han J., Ye H., Tu Y., Chen C., Shi T., Tang Z., J. Mater. Chem. A, 2018, 6(17), 7409
[4] Gao Q. Z., Si F. Y., Zhang S. S., Fang Y. P., Chen X. B., Yang S. Y., Int. J. Hydrog. Energy, 2019, 16(44), 8011
[5] Mittal A., Mari B., Sharma S., Kumari V., Maken S., Kumari K., Kumar N., J. Mater. Sci.-Mater. Electron., 2019, 30(4), 3186
[6] Wang Y., Jia K., Pan Q., Xu Y., Sun X., ACS Sustain. Chem. Eng., 2019, 7(1), 117.
[7] Sotelo-Vazquez C., Noor N., Kafizas A., Quesada-Cabrera R., Scanlon D. O., Taylor A., Durrant J. R., Parkin I. P., Chem. Mat., 2015, 27(9), 3234
[8] Sun X. Y., Zhang X., Sun X., Qian N. X., Wang M., Ma Y. Q., Beilstein J. Nanotechnol., 2019, 10, 2116
[9] Li H. L., Zhang W. J., Liu Y. X., J. Mater. Res. Technol-JMRT, 2020, 2(9), 2557
[10] Dao X., Guo J., Wei Y., Guo F., Liu Y., Sun W., Inorg. Chem., 2019, 58(13), 8517
[11] Hu Q., Di J., Wang B., Ji M., Chen Y., Xia J., Li H., Zhao Y., Appl. Surf. Sci., 2019, 466, 525
[12] Gao Y., Xia J., Liu D., Kang R., Deng S., Chem. Eng. J., 2019, 378, 122118
[13] Chen C., Wu T., Wu H., Liu H., Qian Q., Liu Z., Yang G., Han B., Chem. Sci., 2018, 9(47), 8890
[14] Tran T. V., Cao V. D., Nguyen V. H., Hoang B. N., Vo D. V. N., Nguyen T. D., Bach L. G., J. Environ. Chem. Eng., 2020, 1(8), 102902
[15] Wang J., Xue C., Yao W. Q., Liu J., Gao X. X., Zong R. L., Yang Z., Jin W. J., Tao D. P., Appl. Catal. B:Environ., 2019, 250, 369
[16] Zango Z. U., Bakar N. H. H. A., Sambudi N. S., Jumbri K., Saadet B., J. Environ. Chem. Eng., 2019, 8(2), 103544
[17] Liang Z. B., Qu C., Guo W. H., Zou R. Q., Xu Q., Adv. Mater., 2018, 37(30), 1870276
[18] Wang J., Xue C., Yao W. Q., Liu J., Gao X. X., Zong R. L., Yang Z., Jin W. J., Tao D. P., Appl. Catal. B:Environ., 2019, 250, 369
[19] Zhou A. W., Dou Y. B., Zhao C., Zhou J., Wu X. Q., Li J. R., Appl. Catal. B:Environ., 2020, 264, 118519
[20] Kong X. Q., Li J. Y., Yang C. W., Tang Q., Wang D., Sep. Purif. Technol., 2020, 248, 116924
[21] Dong W. J., Pang G. S., Shi Z., Xu Y. H., Jin H. Y., Shi R., Ma J. J., Feng S. H., Mater. Res. Bull., 2003, 3(39), 433
[22] Xiang G., Li T., Zhuang J., Wang X., Chem. Commun., 2010, 46(36), 6801
[23] Cao X., Zheng B., Rui X., Shi W., Zhang H., Angew. Chem. Int. Ed., 2014, 53(5), 1404
[24] Wang C. C., Wang X., Liu W., Chem. Eng. J., 2020, 391, 123601
[25] Xie D., Ma Y., Gu Y., Zhou H., Zhang H., Wang G., Zhang Y., Zhao H., J. Mater. Chem. A, 2017, 5(45), 23794
[26] Qadir N. U., Said S. A. M., Mansour R. B., Mezghani K., Ul-Hamid A., Dalton. Trans., 2016, 39(45),15621
[27] Li X., Liu P., Mao Y., Xing M., Zhang J., Appl. Catal. B:Environ., 2015, 164, 352
[28] Kim W., Tachikawa T., Kim H., Lakshminarasimhan N., Murugan P., Park H., Majima T., Choi W., Appl. Catal. B:Environ., 2014, 147, 642
[29] Ke F., Qiu L. G., Zhu J. F., Nanoscale, 2014, 3(6), 1596

Synthesis of N-TiO₂@NH₂-MIL-88(Fe) Core-shell Structure for Efficient Fenton Effect Assisted Methylene Blue Degradation Under Visible Light

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