Highly Sensitive and Selective Amperometric Sensor for Iodate Based on 9,10-Phenanthrenequinone Derived Graphene

doi:10.1007/s40242-013-2118-7

Abstract

Abstract:

We reported on a new amperometric sensor for the sensitive and selective determination of iodate in table salt. The iodate sensor was constructed by the integration of a novel nanocomposite which was made from 9,10-phenanthrenequinone(PQ) and graphene(GP) with a glassy carbon electrode(GCE). The synthesized graphene and the nanocomposite were well characterized by X-ray diffraction(XRD), transmission electron microscopy(TEM), Fourier transform infrared(FTIR) spectroscopy and Raman spectroscopy. We fully studied the electrochemical behavior and kinetic characteristics of the PQ/GP nanocomposite at GCE. The PQ/GP electrode shows a good electrochemical catalytic activity towards the reduction of iodate, which makes itself a sensitive and selective electrochemical sensor for iodate. The iodate sensor displays a high sensitivity(1.04 mA·mmol·L^-1), a low detection limit(1.0×10^-8 mol/L), a rapid response(less than 2 s), and a broad linear range(from 5.0×10^-8 mol/L to 6.0×10^-3 mol/L ). In addition, the sensor is interference free. The practical application of the proposed sensor was tested by the detection of iodate in table salt.

Key words: 9,10-Phenanthrenequinone, Graphene, Amperometric sensor, Iodate

WANG Hong-juan, CHENG Na-na, YANG Xiao-yang, LI Xiao-meng, ZHU Lian-de. Highly Sensitive and Selective Amperometric Sensor for Iodate Based on 9,10-Phenanthrenequinone Derived Graphene[J]. Chemical Research in Chinese Universities, 2013, 29(1): 132-138.

References

[1] Greenwood N. N., Earnshaw A., Chemistry of the Element, Pergamon, Oxford, 1984, 533

[2] Gilman A. G., Goodman L. S., Rad T. W., Murad F., The Pharmacological Basis of Therapeutics, 7th Ed., Macmillan, New York, 1985, 745

[3] Chinese Pharmacopoeia Commission, Chinese Pharmacopoeia, 1st Ed., Chemical Industry Press, Beijing, 2000, 970

[4] Shin H. S., Ohshin Y. S., Kim J. H., Ryu J. K., J. Chromatogr. A, 1996, 732, 327

[5] Rahn R. O., Anal. Chim. Acta, 1991, 248, 595

[6] Lefevre G., Bessiere J., Walcarius A., Sens. Actuators B, 1999, 59, 113

[7] Kosminsky L., Bertotti M., Electroanalysis, 1999, 11, 623

[8] Song W. B., Chen X., Jiang Y. X., Liu Y., Sun C. Q., Wang X. H., Anal. Chem. Acta, 1999, 39, 473

[9] Zou B. X., Liu X. X., Diamondc D., Lau K. T., Electrochimica Acta, 2010, 55, 3915

[10] Wang L., Feng Z. G., Cai H. N., J. Electroanal. Chem., 2009, 636, 36

[11] Novoselov K. S., Geim A. K., Morozov S. V., Jiang D., Zhang Y., Dubonos S. V., Grigorieva I. V., Firsov A. A., Science, 2004, 306, 666

[12] Zhang Q., Wu S., Zhang L., Lu J., Verproot F., Liu Y., Xing Z., Song X. M., Biosensors and Bioelectronics, 2011, 26, 2632

[13] Wang H., Tian H. W., Wang X. W., Qiao L., Wang S. M., Wang X. L., Zheng W. T., Liu Y. C., Chem. Res. Chinese Universities, 2011, 27(5), 857

[14] Zhao S. H., Zhao X. T., Fan H. G., Yang L. L., Zhang Y. J., Yang J. H., Chem. Res. Chinese Universities, 2011, 27(4), 547

[15] Zhou Z. J., Li Z. R., Huang X. R., Sun C. C., Chem. Res. Chinese Universities, 2011, 27(3), 512

[16] Geim A. K., Novoselov K. S., Nat. Mater., 2007, 6, 183

[17] Martin P., Chem. Rec., 2009, 9, 211

[18] Liang M., Zhi L., J. Mater. Chem., 2009, 19, 5871

[19] Xu Y., Bai H., Lu G. W., Li C., Shi G. Q., J. Am. Chem. Soc., 2008, 130, 5856

[20] Wang X., Zhi L. J., Müllen K., Nano Lett., 2008, 8, 323

[21] Stoller M. D., Park S. J., Zhu Y. W., An J. H., Ruoff R. S., Nano Lett., 2008, 8, 3498

[22] Ang P. K., Chen W., Wee A. T. S., Loh K. P., J. Am. Chem. Soc., 2008, 130, 14392

[23] Hummers W. S., Offeman R. E., J. Am. Chem. Soc., 1958, 80, 1339

[24] Stankovich S., Dmitriy A. D., Richard D. P., Kevin A. K., Kleinhammes G., Jia Y. Y., Wu Y., SonBinh T. N., Ruoff R. S., Carbon, 2007, 45, 1558

[25] McAllister M. J., Li J. L., Adamson D. H., Schniepp H. C., Abdala A. A., Liu J., Herrera-Alonso M., Milius D. L., Car R., Prud'homme R. K., Aksay I. A., Chem. Mater., 2007, 19, 4396

[26] Si Y., Samulski E. T., Nano Lett., 2008, 8, 1679

[27] Zhou M., Zhai Y. M., Dong S. J., Anal. Chem., 2009, 81, 5603

[28] Wei D. C., Liu Y. Q., Zhang H. L., Huang L. P., Wu B., Chen J. Y., Yu G., J. Am. Chem. Soc., 2009, 131, 11147

[29] Graf D., Molitor F., Ensslin K., Stampfer C., Jungen A., Hierold C., Wirtz L., Nano Lett., 2007, 7, 238

[30] Wang G. X., Yang J., Park J., Gou X. L., Wang B., Liu H., Yao J., J. Phys. Chem. C, 2008, 112, 8192

[31] Brown A. P., Anson F. C., Anal. Chem., 1977, 49, 1589

[32] Sun D. Z., Zhu L. D., Huang H. P., Zhu G. Y., Electroanal. Chem., 2006, 597, 39

[33] Bard A. J., Faulkner L. R., Electrochemical Methods: Fundamentals and Applications, Wiley, New York, 1980

[34] Laviron E., J. Electroanal. Chem., 1979, 101, 19

[35] Salimi A., Noorbakhsh A., Ghadermarzi M., Sens. Actuators B, 2007, 123, 530

[36] Hamidi H., Shama E., Yadollahi B., Talanta, 2008, 74, 909

[37] Lin X., Jiang C., Anal. Sci., 2006, 22, 697

[38] Salimi A., Mamkhezri H., Hallaj R., Electrochim. Acta, 2007, 52, 6097

[39] Huang X., Li Y., Chen Y., Sens. Actuators B, 2008, 134, 780

[40] Salimi A., Mamkhezri H., Mohebbi S., Electrochem. Commun., 2006, 8, 688

[41] Salimi A., Hallaja R., Kavosia B., Hagighic B., Anal. Chim. Acta, 2010, 661, 28

[42] Haghighi B., Hamidi H., Gorton L., Electrochim. Acta, 2010, 55, 4750

[43] Wang Y., Shao Y., Matson D. W., Li J., Lin Y., ACS Nano, 2010, 4, 1790

[44] Zeng Q., Cheng J., Tang L., Liu X., Liu Y., Li J., Jiang J., Advanced Functional Materials, 2010, 20, 3366

[45] Tang L., Wang Y., Li Y., Feng H., Lu J., Li J., Advanced Functional Materials, 2009, 19, 2782 Xu S., Liu Y., Wang T., Li J., Analytical Chemistry, 2011, 83, 3817