Chemical Research in Chinese Universities ›› 2021, Vol. 37 ›› Issue (3): 528-534.doi: 10.1007/s40242-021-1105-7

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Oil-Water Separation Performance of Electrospray Reduced Graphene Oxide Microspheres with a Local Radially Aligned and Porous Structure

YU Ruomeng, SHI Yongzheng, YANG Dongzhi   

  1. Beijing Key Laboratory of Advanced Functional Polymer Composites, College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China
  • Received:2021-03-14 Revised:2021-04-14 Online:2021-06-01 Published:2021-04-16
  • Contact: YANG Dongzhi E-mail:yangdz@mail.buct.edu.cn
  • Supported by:
    This work was supported by the National Natural Science Foundation of China(No.51972015).

Abstract: Micro-size oil adsorbents are effective for the rapid remediation of special oil spills. Here, N-doped reduced graphene oxide(RGO) microspheres(ca. 150 μm in diameter) with a local radially aligned and porous structure are fabricated by combining electrospray-freeze-drying with thermal treatment for rapid separation of oil-water. Owing to its hydrophobic/oleophilic properties and oriented structure, the N-doped RGO microspheres achieve high capacities and fast adsorption rates for a variety of oils and organic solvents. Furthermore, excellent oil-water separation performance on floating oil/oil-water emulsions and stable cyclic adsorption capacities are obtained for the local radially aligned and porous microsphere. Therefore, N-doped RGO microspheres with the unique porous structure have the potential for the remediation of oily sewage and oil spills.

Key words: Electrospray, Radially aligned structure, Microsphere, Reduced graphene oxide, Oil-water separation