Investigation into Experimental Conditions and Factors for Cyclohexane Oxidation with VO(acac)2

doi:10.1007/s40242-014-4188-6

Abstract

Abstract:

The catalytic activity of VO(acac)₂ for the cyclohexane(Cy) oxidation was studied. The effects of various parameters, such as the amounts of H₂O₂, HNO₃, H₂O and Cy were investigated. The highest total turnover number(TON) is 234, which can be increased to 353, 342 and 403, respectively with the adding of o-phthalic, m-phthalic or p-phthalic acid. A reaction mechanism was also supposed primarily.

Key words: VO(acac)₂, Cyclohexane oxidation, Mechanism, Phthalic acid, Additive

MA Xitong, XING Na, WU Qiong, XU Liting, XING Yongheng. Investigation into Experimental Conditions and Factors for Cyclohexane Oxidation with VO(acac)₂[J]. Chemical Research in Chinese Universities, 2014, 30(6): 991-996.

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Investigation into Experimental Conditions and Factors for Cyclohexane Oxidation with VO(acac)₂

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