Highly Efficient Co-removal of Heavy Metals in Wastewater from Chemical Oxygen Demand Testing Instrument by Cysteine-functionalized Magnetic Nanoparticles

doi:10.1007/s40242-014-3484-5

Chemical Research in Chinese Universities ›› 2014, Vol. 30 ›› Issue (3): 472-479.doi: 10.1007/s40242-014-3484-5

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Highly Efficient Co-removal of Heavy Metals in Wastewater from Chemical Oxygen Demand Testing Instrument by Cysteine-functionalized Magnetic Nanoparticles

CAI Botai¹, GU Pei¹, ZENG Lixi¹, ZHOU Ying¹, LIU Qingju¹, LI Xun³, YUAN Longfei¹, HE Yujian^1,2

1. College of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, Beijing 100049, P. R. China;
2. Stake Key Laboratory of Natural and Biomimetic Drugs, Peking University, Beijing 100191, P. R. China;
3. Xinjiang Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Urumqi 830011, P. R. China

Received:2013-11-06 Revised:2014-01-29 Online:2014-06-01 Published:2014-03-05
Contact: ZENG Lixi, HE Yujian E-mail:lxzeng@ucas.ac.cn;heyujian@ucas.ac.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21272263, 21007078, 21377001), the Project of State Key Laboratory of Natural and Biomimetic Drugs, Peking University, China(No.K20130206), the Science Foundation of the Graduated University of Chinese Academy of Sciences(No.O8JT011J01), the National 12th Five-year Plan Supported Project, China (No.2012BAI37B03), the New Star of Science and Technology Supported by Beijing Municipal Science and Technology Commission, China (No.Z131109000413049) and the President Fund of University of Chinese Academy of Sciences(No.Y25101BY00).

Abstract

Abstract:

Wastewater discharged from chemical oxygen demand(COD) testing instrument was generally difficult to treat due to its high content of heavy metals and very low pH. In this study, a kind of cysteine-functionalized magnetic nanoparticles(MNPs-Cys) was synthesized and used to treat the wastewater. The synthesized MNPs-Cys as the adsorbent for heavy metal removal from aqueous solutions were systematically investigated. The adsorption dynamic process fit the Langmuir isotherms well with a maximum adsorption capacity of 76.92 mg/g for Cu(Ⅱ). The adsorbent could be easily regenerated by 0.1 mol/L HNO₃, which exhibited a high adsorption performance within 10 cycles. This adsorbent, combined with a developed pretreatment approach, could make Cr(Ⅲ), Hg(Ⅱ) and Ag(Ⅰ) in the wastewater discharged from COD testing instrument effectively removed and the removal efficiency is more than 99%. This work gave a new insight into the design and synthesis of high-performance materials for treating wastewater with heavy metals.

Key words: Magnetic nanoparticle, Heavy metal, Adsorption, Magnetic separation, Wastewater

CAI Botai, GU Pei, ZENG Lixi, ZHOU Ying, LIU Qingju, LI Xun, YUAN Longfei, HE Yujian. Highly Efficient Co-removal of Heavy Metals in Wastewater from Chemical Oxygen Demand Testing Instrument by Cysteine-functionalized Magnetic Nanoparticles[J]. Chemical Research in Chinese Universities, 2014, 30(3): 472-479.

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Highly Efficient Co-removal of Heavy Metals in Wastewater from Chemical Oxygen Demand Testing Instrument by Cysteine-functionalized Magnetic Nanoparticles

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