Sequential Speciation Analysis of Heavy Metals in Drinking Water Pipe Scales by Mass Spectrometry

doi:10.1007/s40242-022-2131-9

Chemical Research in Chinese Universities ›› 2022, Vol. 38 ›› Issue (3): 774-781.doi: 10.1007/s40242-022-2131-9

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Sequential Speciation Analysis of Heavy Metals in Drinking Water Pipe Scales by Mass Spectrometry

SONG Lili, LI Hui, LI Ting, XU Jiaquan and CHEN Huanwen

Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, East China University of Technology, Nanchang 330013, P. R. China

Received:2022-04-10 Revised:2022-05-04 Online:2022-06-01 Published:2022-05-26
Contact: CHEN Huanwen E-mail:chw8868@gmail.com
Supported by:
This work was supported by the National Natural Science Foundation of China (Nos.21727812, 21705016), the Doctoral Start-up Fund of East China University of Technology, China(No.DHBK2017115), and the Open Fund of Jiangxi Provincial Key Laboratory of Mass Spectrometry Science and Instrumentation, China (No.JXMS202117).

Abstract

Abstract: An electrochemical mass spectrometry technique was developed based on a homemade analytical device for sequential analysis of the heavy metals with various speciations in the scales. Four speciations(e.g., water-soluble speciation, organic speciation, indissoluble speciation and elemental speciation) of heavy metals are sequentially extracted by H₂O, CH₃OH, EDTA-2Na and electrolysis for online electrospray ionization mass spectrometry(ESI-MS) detection. The method takes significant advantages, such as requiring no tedious offline sample pretreatment, high speed of analysis(20 min), high throughput (multi-metals), good sensitivity(0.5 μg/L) and rich chemical information(four speciations). As a result, the rapid comprehensive characterization of four speciations of Pb, Ni, Cu, Zn, Fe, Ba, Mn, Cr and Ca in water pipe scales has been qualitatively achieved. It demonstrated that the present method is a powerful tool for the effective assessment of potential hazards in drinking water, which provides a new analytical idea for evaluating water quality.

Key words: Drinking water pipe scale, Heavy metal speciation analysis, Electrochemical-mass spectrometry, Sequential ionization

SONG Lili, LI Hui, LI Ting, XU Jiaquan and CHEN Huanwen. Sequential Speciation Analysis of Heavy Metals in Drinking Water Pipe Scales by Mass Spectrometry[J]. Chemical Research in Chinese Universities, 2022, 38(3): 774-781.

References

[1] Liu G., Bakker G. L., Li S., Vreeburg J. H. G., Verberk J. Q. J. C., Medema G. J., Liu W. T., van Dijk J. C., Environ. Sci. Technol., 2014, 48(10), 5467
[2] Yang F., Shi B., Zhang W., Cui J., Guo J., Wang D., Wu N., Liu X., Environ. Sci. Pollut. R., 2017. 24(8), 1
[3] Pan L., Li G., Li J., Gao J., Liu Q., Shi B., Sci. Total Environ., 2022. 806, 150549
[4] Qian Y., Characteristics and Control Technology Principles of Water Particulate Matter and Refractory Organic Matter, China Environmental Press, Beijing, 2000
[5] Chen F., Liu W., Pan Z., Wang Y., Guo X., Sun S., Jia R., J. Water Process Eng., 2020, 34, 101191
[6] Zhang H., Zhao L., Liu D., Wang J., Zhang X., Chen C., Water Research, 2020, 176, 115742
[7] Liu G., Zhang Y., Knibbe W.-J., Feng C., Liu W., Medema G., van der Meer W., Water Research, 2017, 116, 135
[8] Debora F., Mohamed T., Jörg S., Adelaide C. M., Serge B., Christian L., Talanta, 2020, 208, 120498
[9] Bi R. X., Li F. L., Chao J. B., Dong H. H., Zhang X. L., Wang Z. H., Li B., Zhao N., J. Chromatogr. A, 2021, 1635, 461712-1
[10] Victor G. M., Pablo D., Linus M. V. M., Sylvain V., Brice B., Jan H. C., J. Anal. Atom. Spectrom., 2020, 35(12), 2852
[11] Liu L. H., Yun Z. J., He B., Jiang G. B., Anal. Chem., 2014, 86, 8167
[12] Dong L. J., Lai Y. J., Yu S. J., Liu J. F., Anal. Chem., 2019, 91, 12525
[13] Foulkes M. E., Sadee B. A., Hill S. J., J. Anal. Atom. Spectrom., 2020, 35(9), 1989
[14] Ferrans L., Jani Y., Burlakovs J., Klavins M., Hogland W., Chemosphere, 2021, 263, 128105-1
[15] Goncalves de Oliveira L. L., Ferreira G. O., Cajamarca Suquila F. A., De Almeida F. G., Bertoldo L. A., Segatelli M. G., Ribeiro E. S., Teixeira Tarley C. R., Food Chem., 2019, 294, 405
[16] Magdalena B., Krzysztof J., Microchem. J., 2022, 172, 106905-1
[17] Munonde T. S., Maxakato N. W., Nomngongo P. N., Microchim. Acta, 2017, 184(4), 1223
[18] Souza S. O., Avila D. V. L., Cerda V., Araujo R. G. O., Food Chem., 2022, 367, 130673-1
[19] Shi Y. P., Liu J. J., Zhang Y., Bao J. F., Cheng J. L., Yi C. Q., Chinese Chem. Lett., 2021, 32(10), 3189
[20] Wiktor L., Anetta H., Adam S., Danuta B., Mass Spectrom. Rev., 2022,41, 32
[21] Indelicato S., Bongiorno D., Ceraulo L., Front. Chem., 2021, 8, 625945
[22] NY/T 1613-2008, Soil Quality-Analysis of Heavy Metals-atomic Absorption Spectrometry with Aqua Regia Digestion, China Agriculture Press, Beijing, 2008
[23] Chen X. M., Zhao Y., Zhang, C., Zhang D. Y., Yao C. H., Meng Q. Q., Zhao R., Wei Z. M., J. Environ. Manage., 2020, 272, 111109
[24] Li J. X., Sun C. J., Zheng L., Jiang F. H., Yin X. F., Chen J. H., Wang X. R., Chinese J. Anal. Chem., 2016, 44(11), 1659

Sequential Speciation Analysis of Heavy Metals in Drinking Water Pipe Scales by Mass Spectrometry

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