Nanostructured Columns from Self-assembly of Complementary Molecular Components

Chemical Research in Chinese Universities ›› 2001, Vol. 17 ›› Issue (2): 193-197.

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Nanostructured Columns from Self-assembly of Complementary Molecular Components

YANG Wen-sheng¹, YANG Bai-quan¹, JIANG Yue-shun¹, LI Tie-jin¹, LIU Ya-Juan²

1. Department of Chemistry, Jilin University, Changchun, 130023, P. R. China;
2. Institute of Information Technology, Jilin Agriculture University, Changchun, 130118, P. R. China

Received:1999-01-18 Online:2001-04-24 Published:2011-08-04
Supported by:
Supported by the National Natural Science Foundation of China.

Abstract

Abstract: Nanostructured columns with a length about several tens of micrometer and a diameter of about 80 nm were obtained by molecular recognition directed self-assembly of a pair of comple mentary molecular components, 4-amino-2,6-didodecylamino-1,3,5-triazine (M) and 5- (4-dode cyloxybenzylidene)-(1H, 3H)-2,4,6-pyrimidinetrione (B) in chloroform. In this system, with positive cooperativity, r-aromatic stacking and van der Waals interactions as well as hydrogen bonds cause the formation of the nanocolumns.

Key words: Nanocolumn, Self-assembly, π-aromatic stacking, Molecular recognition

YANG Wen-sheng, YANG Bai-quan, JIANG Yue-shun, LI Tie-jin, LIU Ya-Juan. Nanostructured Columns from Self-assembly of Complementary Molecular Components[J]. Chemical Research in Chinese Universities, 2001, 17(2): 193-197.

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Nanostructured Columns from Self-assembly of Complementary Molecular Components

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