Promoting Effect of ZnO on the Catalytic Performance of CoZSM-5 for CO2-Assisted Dehydrogenation of Ethane

doi:10.1007/s40242-023-3131-0

Abstract

Abstract: Aseries of ZnO-modified cobaltous ion exchanged ZSM-5 catalysts is prepared using incipient wetness impregnation and characterized by X-ray diffraction (XRD), N₂ adsorption, transmission electron microscopy (TEM), UV-Vis diffuse reflectance spectroscopy (DR UV-Vis), X-ray photoelectron spectroscopy (XPS), pyridine-adsorbed Fourier transform infrared (Py-IR) and Raman. Their catalytic performance towards CO₂-assisted dehydrogenation of ethane to ethylene has been evaluated. The addition of ZnO onto CoZSM-5 obviously improved the yield of ethylene as well as the conversion of CO₂. The promoting effect is attributed to the good activity of ZnO for the reverse water gas shift (RWGS) reaction, which enhances the coupling between RWGS and ethane dehydrogenation.

Key words: Ethane dehydrogenation, CO₂ utilization, ZnO, CoZSM-5, Coupling

HE Huan, ZOU Zhengxi, HUA Weiming, YUE Yinghong, and GAO Zi. Promoting Effect of ZnO on the Catalytic Performance of CoZSM-5 for CO₂-Assisted Dehydrogenation of Ethane[J]. Chemical Research in Chinese Universities, 2023, 39(6): 1064-1069.

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Promoting Effect of ZnO on the Catalytic Performance of CoZSM-5 for CO₂-Assisted Dehydrogenation of Ethane

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