Photocatalytic Stille Cross-coupling on Gold/g-C3N4 Nano-heterojunction

doi:10.1007/s40242-020-0229-5

Abstract

Abstract: Heterogeneous catalysts have been developed for C-C coupling reactions, but stand low activity and always proceed under harsh conditions. Photocatalytic Stille cross-coupling reaction as a green catalytic method for C-C bond formation is of great interest for a wide range of scientists but still lacks stable and highly efficient catalysts. Herein, we have designed an Au nanoparticle-graphitic carbon nitride heterojunction as an outstanding photocatalyst for artificial photosynthesis in Stille cross-coupling reaction. The interface effect between metal and semiconductor makes electron rectify and prevents the recombination of electron-hole pairs. Moreover, the efficiency of Au nanoparticle catalysts could be adjusted by gold contents. Thus the turnover frequency(TOF) value reached the highest level of 788 h^-1 over the optimal heterojunction catalyst. Most importantly, the C-C bond formation reaction has been proved to be carried out well under visible light irradiation, indicating the low-cost organic synthesis process. Further analysis confirmed the stability and general application of our heterogeneous Au nano-heterojunction catalyst.

Key words: Photocatalysis, Stille coupling reaction, Green chemistry, Interface effect

YU Qiuying, LIN Xiu, LI Xinhao, CHEN Jiesheng. Photocatalytic Stille Cross-coupling on Gold/g-C₃N₄Nano-heterojunction[J]. Chemical Research in Chinese Universities, 2020, 36(6): 1013-1016.

References

[1] Xue Z. H., Zhang S. N., Lin Y. X., Su H., Zhai G. Y., Han J. T., Yu Q. Y., Li X. H., Antonietti M., Chen J. S., J. Am. Chem. Soc., 2019, 141, 14976
[2] Shuang S., Lv R., Xie Z., Zhang Z., Sci. Rep., 2016, 6, 26670
[3] Li C. J., Tseng C. M., Lai S. N., Yang C. R., Huang W. H., Nanoscale Res. Lett., 2017, 12, 560
[4] Allen J. E., Hemesath E. R., Perea D. E., Lensch-Falk J. L., Li Z. Y., Yin F., Gass M. H., Wang P., Bleloch A. L., Palmer R. E., Lauhon L. J., Nat. Nanotech., 2008, 3, 168
[5] Shi R., Cao Y., Bao Y., Zhao Y., Waterhouse G. I. N., Fang Z., Wu L. Z., Tung C. H. Yin Y., Zhang T., Adv. Mater., 2017, 29, 1700803
[6] Yu Y., Wen W., Qian X. Y., Liu J. B., Wu J. M., Sci. Rep., 2017, 7, 41253
[7] Li X. H., Antonietti M., Chem. Soc. Rev., 2013, 42, 6593
[8] Zhou C., Shi R., Shang L., Wu L. Z., Tung C. H., Zhang T., Nano Res., 2018, 11, 3462
[9] Jiang S., Xiong C., Song S., Cheng B., ACS Sustainable Chem. Eng., 2019, 7, 2018
[10] Cheng N., Tian J., Liu Q., Ge C., Qusti A. H., Asiri A. M., Al-Youbi A. O., Sun X., ACS Appl. Mater. Interfaces, 2013, 5, 6815
[11] Zada A., Humayun M., Raziq F., Zhang X., Qu Y., Bai L., Qin C., Jing L., Fu H., Adv. Energy Mater., 2016, 6, 1601190
[12] Samanta S., Martha S., Parida K., ChemCatChem, 2014, 6, 1453
[13] Raziq F., Sun L., Wang Y., Zhang X., Humayun M., Ali S., Bai L., Qu Y., Yu H., Jing L., Adv. Energy Mater., 2018, 8, 1701580
[14] Kim Y. M., Yu S., J. Am. Chem. Soc., 2003, 125, 1696
[15] Jin M. J., Lee D. H., Angew. Chem. Int. Ed., 2010, 49, 1119
[16] Cordovilla C., Bartolomé C., Martínez-Ilarduya J. M., Espinet P., ACS Catal., 2015, 5, 3040
[17] Ghorbani-Choghamarani A., Norouzi M., New J. Chem., 2016, 40, 6299
[18] Stratakis M., Garcia H., Chem. Rev., 2012, 112, 4469
[19] Li H., Gao Y., Xiong Z., Liao C., Shih K., Appl. Surf. Sci., 2018, 439, 552
[20] Sengupta D., Saha J., De G., Basu B., J. Mater. Chem. A, 2014, 2, 3986
[21] Zhang X., Xie X., Wang H., Zhang J., Pan B., Xie Y., J. Am. Chem. Soc., 2013, 135, 18
[22] Mohini R., Lakshminarasimhan N., Mater. Res. Bull., 2016, 76, 307
[23] Li X. H., Baar M., Blechert S., Antonietti M., Sci. Rep., 2013, 3, 1743

Photocatalytic Stille Cross-coupling on Gold/g-C₃N₄Nano-heterojunction

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	SONG Weiyu, LV Xintong, GAO Yang, WANG Lu. Photocatalytic HER Performance of TiO₂-supported Single Atom Catalyst Based on Electronic Regulation:A DFT Study [J]. Chemical Research in Chinese Universities, 2022, 38(4): 1025-1031.
[2]	DU Shihao, BIAN Xuanang, ZHAO Yunxuan, SHI Run, and ZHANG Tierui. Progress and Prospect of Photothermal Catalysis [J]. Chemical Research in Chinese Universities, 2022, 38(3): 723-734.
[3]	LIU Shujing, GUO Jia. Two-dimensional Covalent Organic Frameworks: Intrinsic Synergy Promoting Photocatalytic Hydrogen Evolution [J]. Chemical Research in Chinese Universities, 2022, 38(2): 373-381.
[4]	HU Guilin, HE Jingyi, LI Yongjun. Application of Graphdiyne and Its Analogues in Photocatalysis and Photoelectrochemistry [J]. Chemical Research in Chinese Universities, 2021, 37(6): 1195-1212.
[5]	MA Yuying, HE Dayong, LIU Jiadi, WANG Yuannan, YANG Mei, WANG Hao, QIU Ju, LI Wenyan, LI Yongxin, WANG Ce. Adsorption and Visible Light Photocatalytic Degradation of Electrospun PAN@W₁₈O₄₉ Nanofibers [J]. Chemical Research in Chinese Universities, 2021, 37(3): 428-435.
[6]	JIAN Shaoju, TIAN Zhiwei, ZHANG Kaiyin, DUAN Gaigai, YANG Weisen, JIANG Shaohua. Hydrothermal Synthesis of Ce-doped ZnO Heterojunction Supported on Carbon Nanofibers with High Visible Light Photocatalytic Activity [J]. Chemical Research in Chinese Universities, 2021, 37(3): 565-570.
[7]	ZHAO Weifeng, HAO Ning, ZHANG Gai, MA Aijie, CHEN Weixing, ZHOU Hongwei, YANG Dong, XU Ben Bin, KONG Jie. In situ Carbon Modification of g-C₃N₄ from Urea co-Crystal with Enhanced Photocatalytic Activity Towards Degradation of Organic Dyes Under Visible Light [J]. Chemical Research in Chinese Universities, 2020, 36(6): 1265-1271.
[8]	GU Xianmo, MA Pengwei, LIU Pei, WANG Ruiyi, LI Xincheng, ZHENG Zhanfeng. Visible-light-driven Hydroamination of Alkynes over a New Type of Activated Carbon Immobilized Cu²⁺ Photocatalyst [J]. Chemical Research in Chinese Universities, 2020, 36(6): 1039-1044.
[9]	CHEN Ting, ZHONG Lei, YANG Zhen, MOU Zhigang, LIU Lei, WANG Yan, SUN Jianhua, LEI Weiwei. Enhanced Visible-light Photocatalytic Activity of g-C₃N₄/Nitrogen-doped Graphene Quantum Dots/TiO₂ Ternary Heterojunctions for Ciprofloxacin Degradation with Narrow Band Gap and High Charge Carrier Mobility [J]. Chemical Research in Chinese Universities, 2020, 36(6): 1083-1090.
[10]	JIANG Wenshuai, ZONG Xupeng, WANG Xiayan, SUN Zaicheng. Transparent Coating with TiO₂ Nanorods for High-performance Photocatalytic Self-cleaning and Environmental Remediation [J]. Chemical Research in Chinese Universities, 2020, 36(6): 1097-1101.
[11]	CEN Qing, XIAO Wei, LIU Yingqi, WANG Qi, NAFADY Ayman, MA Shengqian. Fabrication of Fe-POMs as Visible-light-active Heterogeneous Photocatalyst [J]. Chemical Research in Chinese Universities, 2020, 36(6): 1128-1135.
[12]	WANG Changhua, ZHANG Xintong. Anatase/Bronze TiO₂ Heterojunction: Enhanced Photocatalysis and Prospect in Photothermal Catalysis [J]. Chemical Research in Chinese Universities, 2020, 36(6): 992-999.
[13]	LI Xiaodong, SU Qing, LIU Ziqian, LUO Kexin, LI Guanghua, WU Qiaolin. A Triformylphloroglucinol-based Covalent Organic Polymer: Synthesis, Characterization and Its Application in Visible-light-driven Oxidative Coupling Reactions of Primary Amines [J]. Chemical Research in Chinese Universities, 2020, 36(6): 1017-1023.
[14]	QI Yinhong, XU Jixiang, WANG Chao, ZHAN Tianrong, WANG Lei. Synthesis of Holey Graphitic Carbon Nitride with Highly Enhanced Photocatalytic Reduction Activity via Melamine-cyanuric Acid Precursor Route [J]. Chemical Research in Chinese Universities, 2020, 36(6): 1024-1031.
[15]	YUAN Huiting, REN Huizhen, LI Minning, LI Zetong, LIU Mingrui, DONG Wenjun, WANG Ge, ZHUANG Tao. Synthesis of N-TiO₂@NH₂-MIL-88(Fe) Core-shell Structure for Efficient Fenton Effect Assisted Methylene Blue Degradation Under Visible Light [J]. Chemical Research in Chinese Universities, 2020, 36(6): 1068-1075.