Synthesis of Pt-SnOx/TS-1@SBA-16 Composites and Their High Catalytic Performance for Propane Dehydrogenation

doi:10.1007/s40242-019-9120-7

Abstract

Abstract: A novel composite material of TS-1@SBA-16 was synthesized by enwrapping TS-1 zeolite crystals with mesoporous SBA-16 silica. This composite was used as catalyst support for loading Pt-SnO_x in the propane dehydrogenation(PDH) reaction. Catalysts were characterized by means of N₂ adsorption-desorption, XRD, SEM, TEM, XPS, UV-Vis, and Raman spectroscopy. The effect of different contents of TS-1 on PDH was investigated, and the optimal amount of TS-1 was determined to be 10%. The catalyst with TS-1 content of 10% showed the highest PDH activity and the initial conversion of propane over it can achieve 54.5%, higher than those over TS-1 or SBA-16-supported ones. The superior catalytic performance of Pt-SnO_x/TS-1@SBA-16 is related to the synergistic effect of the excellent mass transfer performance through the hierarchical porous structure, suitable acid acidity and electronic effect of Ti species.

Key words: Catalyst, Pt-SnO_x, Propane, Dehydrogenation, TS-1 zeolite, Micro-and meso-porous material

LI Hongda, ZHAO Zhen, LI Jiacheng, LI Jianmei, ZHAO Linlin, SUN Jiachen, FAN Xiaoqiang. Synthesis of Pt-SnO_x/TS-1@SBA-16 Composites and Their High Catalytic Performance for Propane Dehydrogenation[J]. Chemical Research in Chinese Universities, 2019, 35(5): 866-873.

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Synthesis of Pt-SnO_x/TS-1@SBA-16 Composites and Their High Catalytic Performance for Propane Dehydrogenation

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