Synthesis of CuⅡ/ZIF-8 Metal-organic Framework Catalyst and Its Application in the Aerobic Oxidation of Alcohols

doi:10.1007/s40242-019-9133-2

Abstract

Abstract: The three-dimensional copper-doped zeolitic imidazolate framework ZIF-8(Cu^Ⅱ/ZIF-8) was prepared by a metal ion exchange process, using reaction of three different copper salts, zinc nitrate hexahydrate[Zn(NO)₃·6H₂O] and 2-methylimidazole(2-MeIM) under nitrogen atmosphere at the room temperature. The TEM and PXRD results indicated that the morphology of Cu^Ⅱ/ZIF-8 was rhombic dodecahedron and the structure was intact after copper was doped into the porous ZIF-8. The synthesized Cu(NO₃)₂/ZIF-8 heterogeneous catalyst showed an excellent activity for the aerobic oxidation of primary alcohols employing molecular oxygen as oxidant. Moreover, the Cu(NO₃)₂/ZIF-8 heterogeneous catalyst can cycled 15 times without leaching of copper.

Key words: Metal organic framework, Heterogeneous catalyst, Molecular oxygen

HOU Junying, HAO Jianjun, WANG Yaya, LIU Jingchun. Synthesis of Cu^Ⅱ/ZIF-8 Metal-organic Framework Catalyst and Its Application in the Aerobic Oxidation of Alcohols[J]. Chemical Research in Chinese Universities, 2019, 35(5): 860-865.

References

[1] Chen B., Wang L. Y., Gao S., ACS Catal., 2015, 5(10), 675
[2] Varma R. S., Saini R. K., Tetrahedron Lett., 1998, 39(12), 1481
[3] Kamimura A., Nozaki Y., Ishikawa S., Inoue R., Nakayama M., Tetrahedron Lett., 2011, 52(4), 538
[4] Jiang H. M., Sun T. Y., Wang X., Xie Y. M., Zhang X. H., Wu Y. D., Schaefer H. F., Org. Lett., 2017, 19(24), 6502
[5] Gogoi N., Begum T., Dutta S., Bora U., Gogoi P. K., RSC Adv., 2015, 5, 95344
[6] Hou J. Y., Luan Y., Tang J., Wensley A. M., Yang M., Lu Y. F., J. Mol. Catal. A:Chem., 2015, 407, 53
[7] Zhang G. S., Xing X. F., Guan Y., Zhou A. Q., Zhang X. M., Xu X. H., Repo T., Chem. J. Chinese Universities, 2013, 34(4), 900
[8] Zavahir S., Xiao Q., Sarina S., Zhao J., Bottle S., Wellard M., Jia J. F., Jing L. Q., Huang Y. M., Blinco J. P., Wu H. S., Zhu H. Y., ACS Catal., 2016, 6(6), 3580
[9] Dutta D., Phukan A., Dutta D. K., Mol. Catal., 2018, 451, 178
[10] Iron M. A., Szpilman A. M., Chem. Eur. J., 2017, 23, 1368
[11] Semmelhack M. F., Schmid C. R., Cortes D. A., Chou C. S., J. Am. Chem. Soc., 1984, 106, 3374
[12] Xie X. M., Stahl S. S., J. Am. Chem. Soc., 2015, 137, 3767
[13] Chandra P., Jonas A. M., Fernandes A. E., ACS Catal., 2018, 8(7), 6006
[14] Vanoye L., Pablos M., de Bellefon C., Favre-Reguillon A., Adv. Synth. Catal., 2015, 357, 739
[15] Solomon E. I., Stahl S. S., Chem. Rev., 2018, 118, 2299
[16] Grayson J. D., Partridge B. M., ACS Catal., 2019, 9(5), 4296
[17] Corma A., Angew. Chem. Int. Ed., 2016, 55, 6112
[18] Parmeggiani C., Matassini C., Cardona F., Green Chem., 2017, 19, 2030
[19] Li F. H., Hu D. R., Yuan Y. H., Luo B. B., Song Y. B., Xiao S. T., Chen G. H., Fang Y. W., Lu F. S., Mol. Catal., 2018, 452, 75
[20] Dhakshinamoorthy A., Asiri A. M., Garcia H., Chem. Commun., 2017, 53, 10851
[21] Kirchon A., Feng L., Drake H. F., Joseph E. A., Zhou H. C., Chem. Soc. Rev., 2018, 47, 8611
[22] Kalmutzki M. J., Hanikel N., Yaghi O. M., Sci. Adv., 2018, 4, 9180
[23] Furukawa H., Ko N., Go Y. B., Aratani N., Choi S. B., Choi E., Yazaydin A. O., Snurr R. Q., O'Keeffe M., Kim J., Yaghi O. M., Science, 2010, 329, 424
[24] Zhao J., Wang W. Y., Tang H. L., Ramella D., Luan Y., Mol. Catal., 2018, 456, 57
[25] Xue D. X., Belmabkhout Y., Shekhah O., Jiang H., Adil K., Cairna A. J., Eddaoudi M., J. Am. Chem. Soc., 2015, 137, 5034
[26] Li Y. A., Zhao C. W., Zhu N. X., Liu Q. K., Chen G. J., Liu J. B., Zhao X. D., Ma J. P., Zhang S. J., Dong Y. B., Chem. Commun., 2015, 51, 17672
[27] Dhakshinamoorthy A., Asiri A. M., Garcia H., Chem. Eur. J., 2016, 22, 8012
[28] Chen S. C., Li N., Tian F., Chai N. N., He M. Y., Chen Q., Mol. Catal. 2018, 450, 104
[29] Kumar P., Pournara A., Kim K. H., Bansal V., Rapti S., Manos M. J., Prog. Mater. Sci., 2017, 86, 25
[30] Noori Y., Akhbari K., RSC Adv., 2017, 7, 1782
[31] Marshall R. J., Forgan R. S., Eur. J. Inorg. Chem., 2016, 27, 4310
[32] Fu Y. H., Xu L., Shen H. M., Yang H., Zhang F. M., Zhu W. D., Fan M. H., Chem. Eng. J., 2016, 299, 135
[33] Sun D. R., Sun F. X., Deng X. Y., Li Z. H., Inorg. Chem., 2015, 54, 8639
[34] Stubbs A. W., Braglia L., Borfecchia E., Meyer R. J., Roman-Leshkov Y., Lamberti C., Dinca M., ACS Catal., 2018, 8(1), 596
[35] Kida K., Okita M., Fujita K., Tanaka S., Miyake Y., CrystEngComm., 2013, 15, 1794
[36] Bai L., Li M., Guan J. Q., Chemistry Select., 2018, 3, 581
[37] Zhang X. W., Huang N., Wang G., Dong W. J., Yang M., Luan Y., Shi Z., Micropor. Mesopor. Mat., 2013, 177, 47
[38] Schejn A., Aboulate A., Balan L., Falk V., Lavevee J., Medjahdi G., Aranda L., Mozet K., Schneider R., Catal. Sci. Technol., 2015, 5, 1829
[39] Du P. C., Dong Y. N., Liu C., Wei W. L., Liu D., Liu P., J. Colloid Interf. Sci., 2018, 518, 57
[40] Ethiraj J., Bonino F., Lamberti C., Bordiga S., Micropor. Mesopor. Mat., 2015, 207, 90
[41] Li Y., Wee L. H., Martens J. A., Vankelecom I. F. J., J. Memb. Sci., 2017, 523, 561
[42] Wu C. S., Xiong Z. H., Li C., Zhang J. M., RSC Adv., 2015, 5, 82127
[43] James J. B., Lin Y. S., J. Phys. Chem. C, 2016, 120, 14015
[44] Hou J. Y., Luan Y., Yu J., Qi Y., Wang G., Lu Y. F., New J. Chem., 2016, 40, 10127
[45] Wang J. J., Liu C. S., Chang Z., Yan L. F., Bu X. H., Chinese J. Inorg. Chem., 2006, 22, 8
[46] Gamez P., Arends I. W. C. E., Reedijk J., Sheldon R. A., Chem. Commun., 2003, 2142
[47] Luan Y., Qi Y., Gao H. Y., Zheng N. N., Wang G., J. Mater. Chem. A, 2014, 2, 20588

Synthesis of Cu^Ⅱ/ZIF-8 Metal-organic Framework Catalyst and Its Application in the Aerobic Oxidation of Alcohols

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