Rapid Microwave-assisted Hydrothermal Synthesis of SrWO4:Eu3+ Nanowires and Their Luminescence Properties

doi:10.1007/s40242-015-4448-0

Chemical Research in Chinese Universities ›› 2015, Vol. 31 ›› Issue (2): 175-178.doi: 10.1007/s40242-015-4448-0

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Rapid Microwave-assisted Hydrothermal Synthesis of SrWO₄:Eu³⁺ Nanowires and Their Luminescence Properties

LÜ Yang¹, YANG Min¹, YANG Bin², LIU Wei¹, ZHANG Hongdan¹, ZHAO Xudong¹, LIU Xiaoyang¹

1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, P. R. China;
2. School of Materials Science and Engineering, Anhui University of Technology, Maanshan 243002, P. R. China

Received:2014-11-27 Revised:2015-02-02 Online:2015-04-01 Published:2015-02-12
Contact: ZHAO Xudong, LIU Xiaoyang E-mail:liuxy@jlu.edu.cn;xdzhao@jlu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21271082, 21371068) and the China Postdoctoral Science Foundation(No.801141080411).

Abstract

Abstract:

SrWO₄:Eu³⁺ nanowires were synthesized at 160 ℃ within 10 min via a microwave-assisted hydrothermal method. In examining the influences of synthesis temperature and reaction time on the morphology of nanowires, it was found that any temperatures and reaction time except 160 ℃ and 10 min gave rise to poorer morphologies under otherwise equal conditions. The synthesized nanowires were characterized by means of X-ray diffraction(XRD), scanning electron microscopy(SEM), transmission electron microscopy(TEM), high-resolution transmission electron microscopy(HRTEM), energy dispersive X-ray(EDX) and Raman spectrometry, respectively. The results suggest that the samples are homogenous and dispersive single phase nanowires. The photoluminescence properties of the nanowires were determined with a spectrofluorometer. Two obviously sharp peaks at 395 and 464 nm and a broad peak centered at 290 nm were found in their excitation spectrum. Under excitation at 395 and 464 nm , the ⁵D₀→⁷F₂ transition is the dominant process which means Eu³⁺ ion is located at a low symmetry site, while the ⁵D₀→⁷F₁ transition dominates under the excitation at 290 nm, showing a highly symmetric field around the Eu³⁺ ion, which indicates the presence of the two local Eu³⁺ environments.

Key words: SrWO₄:Eu³⁺ nanowire, Microwave-assisted hydrothermal method, Luminescence property

LÜ Yang, YANG Min, YANG Bin, LIU Wei, ZHANG Hongdan, ZHAO Xudong, LIU Xiaoyang. Rapid Microwave-assisted Hydrothermal Synthesis of SrWO₄:Eu³⁺ Nanowires and Their Luminescence Properties[J]. Chemical Research in Chinese Universities, 2015, 31(2): 175-178.

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Rapid Microwave-assisted Hydrothermal Synthesis of SrWO₄:Eu³⁺ Nanowires and Their Luminescence Properties

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