Synthesis and Structural Determination of Binuclear Nine-Coordinate K4[Y2(Httha)2]·14H2O

Chemical Research in Chinese Universities ›› 2002, Vol. 18 ›› Issue (3): 237-241.

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Synthesis and Structural Determination of Binuclear Nine-Coordinate K₄[Y₂(Httha)₂]·14H₂O

WANG Jun, ZHANG Xiang-dong, MA Rui

Department of Chemistry, Liaoning University, Shenyang 110036, P. R. China

Received:2001-06-20 Online:2002-08-24 Published:2011-08-04
Supported by:
Supported by the National Science Foundation of Liaoning Province Science and Technology Committee(No.9810300901).

Abstract

Abstract: A Y³⁺ complex with triethylenetetraaminehexaacetic acid was prepared and its composition and structure were determined as K₄[Y₂(Httha)₂]·14H₂O by elemental analysis and single-crystal X-ray four circle diffraction analysis. In the binuclear complex, the two YN₃O₆ parts all form nine-coordinate monocapped square anti prismatic structures. There are a lot of water molecules in the unit cell which form hydrogen bonds.

Key words: Y³⁺, Triethylenetetraaminehexaacetic acid, Binuclear complex, Structure

WANG Jun, ZHANG Xiang-dong, MA Rui. Synthesis and Structural Determination of Binuclear Nine-Coordinate K₄[Y₂(Httha)₂]·14H₂O[J]. Chemical Research in Chinese Universities, 2002, 18(3): 237-241.

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Synthesis and Structural Determination of Binuclear Nine-Coordinate K₄[Y₂(Httha)₂]·14H₂O

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