Researches into the Proton Conductivity of Molybdovanadophosphoric Acids with Wells-Dawson Structure

Chemical Research in Chinese Universities ›› 1996, Vol. 12 ›› Issue (4): 322-325.

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Researches into the Proton Conductivity of Molybdovanadophosphoric Acids with Wells-Dawson Structure

WANG En-bo, LI Bai-tao, WANG Zuo-ping, ZHANG Bao-jian

Department of Chemistry, Northeast Normal University, Changchun, 130024

Received:1995-12-26 Online:1996-12-24 Published:2011-08-17
Supported by:
Supported by the National Natural Science Foundation of China.

Abstract

Abstract: Five kinds of molybdovanadophosphoric acids H₇[P₂Mo₁₇VO₆₂],H₈[P₂Mo₁₆·V₂O₆₂],H₉ [P₂Mo₁₅V₃O₆₂],H₈[P₂Mo₁₄V₄O₆₁(H₂O)]and H₉[P₂Mo₁₃V₅O₆₁(H₂O)]have been synthesized.Their protop conductivities(C) have been measured.The effects of three main factors (frequency,hydration numbers,temperature)on the conductivity have been investigated.In some degree,heteropoly compounds with different structures give a different conductivity.

Key words: Proton conductivity, Heteropoly acid, Polarization, Molyb dovanadophosphoric acid

WANG En-bo, LI Bai-tao, WANG Zuo-ping, ZHANG Bao-jian. Researches into the Proton Conductivity of Molybdovanadophosphoric Acids with Wells-Dawson Structure[J]. Chemical Research in Chinese Universities, 1996, 12(4): 322-325.

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Researches into the Proton Conductivity of Molybdovanadophosphoric Acids with Wells-Dawson Structure

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