Introduction of H2SO4 and H3PO4 into Crystalline Porous Organic Salts(CPOS-1) for Outstanding Proton Conductivity

doi:10.1007/s40242-020-9276-1

Chemical Research in Chinese Universities ›› 2020, Vol. 36 ›› Issue (5): 976-980.doi: 10.1007/s40242-020-9276-1

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Introduction of H₂SO₄ and H₃PO₄ into Crystalline Porous Organic Salts(CPOS-1) for Outstanding Proton Conductivity

WANG Yuxia¹, YAN Tingting^1,2, BEN Teng¹

1. Department of Chemistry, Jilin University, Changchun 130012, P. R. China;
2. Shandong Key Laboratory of Biophysics, Institute of Biophysics, Dezhou University, Dezhou 253023, P. R. China

Received:2019-10-11 Revised:2019-12-17 Online:2020-10-01 Published:2020-10-01
Contact: BEN Teng E-mail:tben@jlu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.91956108, 21871103), the "111" Project, China (No.BP0719036) and the Foundation of the Science and Technology Department of Jilin Province, China(No.20180414009GH).

Abstract

Abstract: To improve the proton conduction of crystalline porous organic salts(CPOS-1), H₂SO₄ and H₃PO₄ were introduced into the channel to obtain H₂SO₄@CPOS-1 and H₃PO₄@CPOS-1. Compared to CPOS-1, the proton conductivities of H₂SO₄@CPOS-1 and H₃PO₄@CPOS-1 increased two orders of magnitude and one order of magnitude at 303 K and 100% RH, respectively. It can be attributed to the increasing concentration of the protons, which dissociates from the acids.

Key words: Proton conductivity, Crystalline porous organic salt, H₂SO₄, H₃PO₄

WANG Yuxia, YAN Tingting, BEN Teng. Introduction of H₂SO₄ and H₃PO₄ into Crystalline Porous Organic Salts(CPOS-1) for Outstanding Proton Conductivity[J]. Chemical Research in Chinese Universities, 2020, 36(5): 976-980.

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Introduction of H₂SO₄ and H₃PO₄ into Crystalline Porous Organic Salts(CPOS-1) for Outstanding Proton Conductivity

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