Studies of Mixed-valence Compounds(Ⅰ)──In-Situ FTIR and UV-Visible-Near-IR Spectroelectrochemical Studies of Mixed-valence Isopolyanion Mo6O193-in Aprotic Media

Abstract

Abstract: The mixed-valence isopolyanion Mo₆O₁₉^3-was investigated by means of cyclic voltammographic, in-situ FTIR and UV-Visible-Near-IR spectro-electrochemicalmethods in aprotic media. The experimental results indicate that the Mo₆O₁₉^3-was formed whereafter Mo₆O₁₉^3-was reduced, (E^0'=- 0. 690 V, n=1). The characteristic absorptions of Mo_{6O₁₉^3-are 500 nm, 900 nm and 1100 nm in UV-VisibleNear-IRspectrum and 940 cm^-1in IRspectrum.}

Key words: Mixed-valence compound, Electrochemistry, In-situ spectro-electrochemistry

SUN Hao-ran, YANG Guo-yu, XU Jia-ning, XU Ji-qing . Studies of Mixed-valence Compounds(Ⅰ)──In-Situ FTIR and UV-Visible-Near-IR Spectroelectrochemical Studies of Mixed-valence Isopolyanion Mo₆O₁₉^3-in Aprotic Media[J]. Chemical Research in Chinese Universities, 1996, 12(1): 6-9.

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Studies of Mixed-valence Compounds(Ⅰ)──In-Situ FTIR and UV-Visible-Near-IR Spectroelectrochemical Studies of Mixed-valence Isopolyanion Mo₆O₁₉^3-in Aprotic Media

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