Chemical Research in Chinese Universities ›› 1993, Vol. 9 ›› Issue (1): 40-44.

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Studies on Silicon-Containing Fragrance Raw Materials(Ⅲ)——The Addition of5-Trimethylsilylcyclohex-3-enone with Grignard Reagent

TANG Shi-xiong, XUE Jie-you, DUAN Mao-sheng, CAO Yu-rong, ZHI Jin-fang, WANG Xiao-Ian   

  1. Department of Chemistry, Nankai University, Tianjin, 300071
  • Received:1992-04-23 Online:1993-01-24 Published:2011-08-17
  • Supported by:

    Supported by the National Natural Science Foundation of China; Youth Foundation of Tianjin

Abstract: The present paper narrates the addition of 5-trimethylsilylcyclohex-3-enone to Grig-nard reagent to give 1-substituted 5-trimethylsilylcyclohex-3-enol in a good yield. The stereochemistry of the addition reaction and their products are discussed.

Key words: 5-trimethylsilylcyclohex-3-enone, Grignard reagent, Addition, Stereochemistry