Solid-state[2+2] Photocycloaddition Reaction of Zinc(II) Complex Based on Quaternized 1,2-Bis(4'-pyridyl) ethylene

doi:10.1007/s40242-021-1226-z

Chemical Research in Chinese Universities ›› 2022, Vol. 38 ›› Issue (1): 181-185.doi: 10.1007/s40242-021-1226-z

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Solid-state[2+2] Photocycloaddition Reaction of Zinc(II) Complex Based on Quaternized 1,2-Bis(4'-pyridyl) ethylene

JIA Mengze¹, SUN Li², CHEN Yunrui¹, ZHANG Jie¹

1. MOE Key Laboratory of Cluster Science, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 102488, P. R. China;
2. College of Chemical Engineering, Shijiazhuang University, Shijiazhuang 050035, P. R. China

Received:2021-05-23 Revised:2021-07-01 Online:2022-02-01 Published:2021-07-02
Contact: ZHANG Jie E-mail:zhangjie68@bit.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China(Nos.21871027 and 21573016).

Abstract

Abstract: Aphotoactive metal-organic complex[Zn₂(BCbpe)₂(p-DBC)₂]∙

5H₂O(1) has been synthesized based on an olefin-containing pyridinium compound, 1-(4-carboxybenzyl)-4-[2-(4-pyridyl)-vinyl]pyridinium chloride(HBCbpeCl), and characterized by single-crystal X-ray diffraction, IR spectroscopy, powder X-ray diffraction and thermogravimetric analysis, respectively. In the solid state, the BCbpe ligands are packed in a head-to-tail manner through weak cation-π interaction, undergoing a photo-induced cycloaddition quantitatively upon UV-light irradiation.

Key words: [2+2] cycloaddition, Pyridinium, Solid-state photo-reaction

JIA Mengze, SUN Li, CHEN Yunrui, ZHANG Jie. Solid-state[2+2] Photocycloaddition Reaction of Zinc(II) Complex Based on Quaternized 1,2-Bis(4'-pyridyl) ethylene[J]. Chemical Research in Chinese Universities, 2022, 38(1): 181-185.

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Solid-state[2+2] Photocycloaddition Reaction of Zinc(II) Complex Based on Quaternized 1,2-Bis(4'-pyridyl) ethylene

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