Structure of Palladium(Ⅱ) Complex with 2-Hydroxy-propane 1, 3-diamine-N,N,N',N'-tetraacetic Acid

Chemical Research in Chinese Universities ›› 1992, Vol. 8 ›› Issue (4): 399-404.

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Structure of Palladium(Ⅱ) Complex with 2-Hydroxy-propane 1, 3-diamine-N,N,N',N'-tetraacetic Acid

SONG Rui-fang¹, ZHANG Cun-zhi¹, LI Fei¹, JIN Song-chun², JTN Zhong-sheng²

1. Institute of Theoretical Chemistry, Jilin University, Changchun, 130023;
2. Changchun Institute of Applied Chemistry, Academia Sinica, Changchun, 130022

Received:1991-12-11 Online:1992-12-24 Published:2011-08-17
Supported by:
Supported by the National Natural Science Foundation of China

Abstract

Abstract: The reaction of PdCl₂in water with 2-hydroxypropane-1, 3-diaminetetraacetic acid (HPDTA) gave the complex Pd (C₁₁H₁₆N₂O₉)·1. 5H₂O, which was characterized by elemental analysis, IR, NMR and single-crystal X-ray diffraction. The spectroscopic and X-ray diffraction data show that Pd (Ⅱ) is coordinated by two nitrogen atoms and two car-boxylic oxygen atoms. The complex crystallizes in monoclinic space group P_cwith a=1. 1240(2), b=1. 1183(2), c=1. 2597(3) nm, β=96. 33(2)°V=1. 5737(6) nm³, Z=4, R=0.038. The structure contains two crystallographically independent molecules which have slightly different orientations and are connected by hydrogen bonds.

Key words: Structure, Pd(Ⅱ)-HPDTA, Complex

SONG Rui-fang, ZHANG Cun-zhi, LI Fei, JIN Song-chun, JTN Zhong-sheng. Structure of Palladium(Ⅱ) Complex with 2-Hydroxy-propane 1, 3-diamine-N,N,N',N'-tetraacetic Acid[J]. Chemical Research in Chinese Universities, 1992, 8(4): 399-404.

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Structure of Palladium(Ⅱ) Complex with 2-Hydroxy-propane 1, 3-diamine-N,N,N',N'-tetraacetic Acid

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