The Study of Oxygen Transfer Kinetics for MoO2(S2CENt2)2 in Various Solvents

Abstract

Abstract: The reaction kinetics between MoO₂(S₂CNEt₂)₂ and triphenylphos-phine (PPh₃) were studied in various organic solvents with the aid of the stopped-flow technique. The linear correlations were found for rate constants or activation energy versus the function of refractive index (n²- 1)/(2n² + 1). It was also found that pre-factor increases with the descent of ( n² - l)/(2n² - 1) slightly.One step mechanism which supposes the lone pair of electrons on P atom of triphenylphosphine enters directly into the Ⅱ^* antibonding orbital, which makes the Mo= O bond broken, is suggested.

Key words: Rate constant, Activation energy, Pre-factor, Refractive index, Mechanism, Anti bond orbital

Yang Huixing, Chen Yu, He Hong. The Study of Oxygen Transfer Kinetics for MoO₂(S₂CENt₂)₂ in Various Solvents[J]. Chemical Research in Chinese Universities, 1988, 4(2): 85-90.

[1]	HU Shifan, WANG Yafeng and SU Bin. Effect of Ionic Strength on the Electrochemiluminescence Generation by Tris(2,2'-bipyridyl)ruthenium(II)/Tri-n-propylamine [J]. Chemical Research in Chinese Universities, 2022, 38(3): 816-822.
[2]	LI Siying, PAN Yangang, TENG Honggang, SHAN Yuping, YANG Guocheng, and WANG Hongda. Revealing the Cell Entry Dynamic Mechanism of Single Rabies Virus Particle [J]. Chemical Research in Chinese Universities, 2022, 38(3): 838-842.
[3]	ZHANG Xiaosi, YANG Miao, TIAN Peng, LIU Zhongmin. Progress in Seed-assisted Synthesis of (Silico) Aluminophosphate Molecular Sieves [J]. Chemical Research in Chinese Universities, 2022, 38(1): 1-8.
[4]	ZHOU Xue, WANG Chao, CHU Yueying, WANG Qiang, XU Jun, DENG Feng. Mechanistic Insight into Ethanol Dehydration over SAPO-34 Zeolite by Solid-state NMR Spectroscopy [J]. Chemical Research in Chinese Universities, 2022, 38(1): 155-160.
[5]	XU Haijiao, WANG Hongda. Conventional Molecular and Novel Structural Mechanistic Insights into Orderly Organelle Interactions [J]. Chemical Research in Chinese Universities, 2021, 37(4): 829-839.
[6]	ZHANG Jianyu, ZHANG Haoke, LAM Jacky W. Y., TANG Ben Zhong. Restriction of Intramolecular Motion(RIM): Investigating AIE Mechanism from Experimental and Theoretical Studies [J]. Chemical Research in Chinese Universities, 2021, 37(1): 1-15.
[7]	WANG Lipeng, LIU Leijing, XU Bin, TIAN Wenjing. Recent Advances in Mechanism of AIE Mechanochromic Materials [J]. Chemical Research in Chinese Universities, 2021, 37(1): 100-109.
[8]	ZHAO Yangyang, LI Huangong, SUN Pengwei, GAO Li, ZHOU Sha, XIONG Lixia, YANG Na, LI Yuxin, LI Zhengming. Design, Synthesis, Biological Evaluation and SARs of Anthranilic Diamide Derivatives Containing Pyrrole Moieties [J]. Chemical Research in Chinese Universities, 2020, 36(6): 1168-1173.
[9]	YU Bowen, LOU Caiyi, ZHANG Wenna, XU Shutao, HAN Jingfeng, YU Zhengxi, WEI Yingxu, LIU Zhongmin. Insight into the Dual Cycle Mechanism of Methanol-to-Olefins Reaction over SAPO-34 Molecular Sieve by Isotopic Tracer Studies [J]. Chemical Research in Chinese Universities, 2020, 36(6): 1203-1208.
[10]	LIU Yuanyuan, LI Yi, ZONG Linghui, ZHANG Jingyi. Comparison of Two Rhodamine-Polyamine Polystyrene Solid-phase Fluorescence Sensors for Hg(II) Detection Based on Theoretical Calculation [J]. Chemical Research in Chinese Universities, 2020, 36(5): 781-786.
[11]	PAN Lu, DONG Jinyang, YI Ding, YANG Yijun, WANG Xi. Recent Advances in Atomic-scale Storage Mechanism Studies of Two-dimensional Nanomaterials for Rechargeable Batteries Beyond Li-ion [J]. Chemical Research in Chinese Universities, 2020, 36(4): 560-583.
[12]	WANG Haitao, TANG Yongbing. Artificial Solid Electrolyte Interphase Acting as “Armor” to Protect the Anode Materials for High-performance Lithium-ion Battery [J]. Chemical Research in Chinese Universities, 2020, 36(3): 402-409.
[13]	CHEN Jianyu, XU Xin, HE Qian, MA Yanwen. Advanced Current Collectors for Alkali Metal Anodes [J]. Chemical Research in Chinese Universities, 2020, 36(3): 386-401.
[14]	YANG Peihua, FAN Hongjin. Electrochemical Impedance Analysis of Thermogalvanic Cells [J]. Chemical Research in Chinese Universities, 2020, 36(3): 420-424.
[15]	WANG Shuxin, CAO Jian, CHENG Yuxiao, LU Chenhong. A Sensitive Fluorescent Turn-on Probe NapP-deap Based on Naphthalimide Derivative to Detect Hg(II) Ions in HEPES Buffer Solution and Living Cells [J]. Chemical Research in Chinese Universities, 2019, 35(6): 967-971.

The Study of Oxygen Transfer Kinetics for MoO₂(S₂CENt₂)₂ in Various Solvents

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments