Template Effect of Hydrophobically Associating Polymers on theConstruction of Cuprous Oxide Micro Structure

doi:10.1007/s40242-018-7173-7

Chemical Research in Chinese Universities ›› 2018, Vol. 34 ›› Issue (1): 138-144.doi: 10.1007/s40242-018-7173-7

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Template Effect of Hydrophobically Associating Polymers on theConstruction of Cuprous Oxide Micro Structure

DONG Lei¹, LIU Huan¹, LI Yanjuan², ZHANG Hongtao¹, YU Liangmin¹, JIA Lanni^3,4

1. Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, P. R. China;
2. School of Chemistry and Chemical Engineering, Jiangsu Normal University, Xuzhou 221116, P. R. China;
3. National Engineering Research Center for Marine Drugs, Ocean University of China, Qingdao 266071, P. R. China;
4. Marine Biomedical Research Institute of Qingdao, Qingdao 266071, P. R. China

Received:2017-05-15 Online:2018-02-01 Published:2018-01-20
Contact: YU Liangmin,E-mail:yuyan@ouc.edu.cn;JIA Lanni,E-mail:jialann@163.com E-mail:yuyan@ouc.edu.cn;jialann@163.com
Supported by:
Supported by the National Natural Science Foundation of China(No.51102219) and the Fundamental Research Funds for the Central Universities of China(Nos.201113024, 41404010204).

Abstract

Abstract: To determine the template effect of hydrophobically associating copolymers(HACPs) on the morphology of nano/micro structures, six HACPs were synthesized and used as templates to biomimetically synthesize cuprous oxide(Cu₂O), an important semiconductor. This experiment showed a clear relationship between the associating state of the HACP molecules and the morphology of the Cu₂O particles. Cu₂O hollow spheres were preferentially prepared when the HACP molecules were in an intramolecular associating state. Furthermore, a Cu₂O hexapod was easily obtained when the HACP molecules were in an intermolecular associating state. The morphologies of the Cu₂O crystals prepared in the presence of the HACPs also confirmed this result.

Key words: Template, Hydrophobically associating polymer, Cuprous oxide, Morphology

DONG Lei, LIU Huan, LI Yanjuan, ZHANG Hongtao, YU Liangmin, JIA Lanni. Template Effect of Hydrophobically Associating Polymers on theConstruction of Cuprous Oxide Micro Structure[J]. Chemical Research in Chinese Universities, 2018, 34(1): 138-144.

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Template Effect of Hydrophobically Associating Polymers on theConstruction of Cuprous Oxide Micro Structure

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