Synthesis Optimization of SSZ-13 Zeolite Membranes by Dual Templates for N2/NO2 Separation

doi:10.1007/s40242-021-1420-z

Chemical Research in Chinese Universities ›› 2022, Vol. 38 ›› Issue (1): 250-256.doi: 10.1007/s40242-021-1420-z

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Synthesis Optimization of SSZ-13 Zeolite Membranes by Dual Templates for N₂/NO₂ Separation

LI Jun¹, RONG Huazhen², CHEN Cong³, LI Ziyi¹, ZUO Jiayu¹, WANG Wenjian², LIU Xinjian¹, GUAN Yixing², YANG Xiong¹, LIU Yingshu¹, ZOU Xiaoqin², ZHU Guangshan²

1. School of Energy and Environmental Engineering, University of Science and Technology Beijing, Beijing 100083, P. R. China;
2. Faculty of Chemistry, Northeast Normal University, Changchun 130024, P. R. China;
3. Science and Technology on Reactor System Design Technology Laboratory, Nuclear Power Institute of China, Chengdu 610213, P. R. China

Received:2021-10-17 Revised:2021-11-16 Online:2022-02-01 Published:2021-11-16
Contact: LI Ziyi, ZOU Xiaoqin E-mail:ziyili@ustb.edu.cn；zouxq100@nenu.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (Nos.21808012, 21971035), the "111" Project of China(No.B18012), and the Open Project of the National Defense Science and Technology Industry Nuclear Power Technology Innovation Center of China(No.HDLCXZX-2020-HD-005).

Abstract

Abstract: High-silica SSZ-13 zeolite membranes are promising in industrial separations of light gases and continuous membranes are highly demanded for better separation performances. Herein, pure-phase, continuous and thin SSZ-13 zeolite membranes were synthesized using dual templates of N,N,N-trimethtyl-1-adamantammonium hydroxide(TMAdaOH) and tetraethylammonium hydroxide(TEAOH). Systematical investigations of TMAdaOH/TEAOH ratios and their concentrations show that TMAdaOH acts as the main structure-directing agent in the formation of the SSZ-13 zeolite. TMAdaOH cooperatively plays with TEAOH in promoting the SSZ-13 crystal intergrowth to form a continuous polycrystalline membrane. Additionally, appropriate introduction of TEAOH is able to adjust the membrane thickness to the crystal-comparable size of ca. 2.0 μm. The SSZ-13 membranes are further applied for N₂/NO₂separation, which is firstly reported on zeolite membranes. The gas permeation results show that the SSZ-13 membrane synthesized by the dual-template approach exhibits selective separation of N₂ over NO₂ with N₂/NO₂ separation factor of 7.6 and N₂ permeance of 1.66×10^-8 mol·m^-2·s^-1·Pa^-1.

Key words: Zeolite membrane, Dual template, SSZ-13, Gas separation, Nitrogen dioxide

LI Jun, RONG Huazhen, CHEN Cong, LI Ziyi, ZUO Jiayu, WANG Wenjian, LIU Xinjian, GUAN Yixing, YANG Xiong, LIU Yingshu, ZOU Xiaoqin, ZHU Guangshan. Synthesis Optimization of SSZ-13 Zeolite Membranes by Dual Templates for N₂/NO₂ Separation[J]. Chemical Research in Chinese Universities, 2022, 38(1): 250-256.

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Synthesis Optimization of SSZ-13 Zeolite Membranes by Dual Templates for N₂/NO₂ Separation

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