Effect of Reaction Conditions on the Assembly, Structures and Fluorescent Sensing Behaviors of Cd(Ⅱ) Metal-organic Complexes

doi:10.1007/s40242-016-5288-2

Chemical Research in Chinese Universities ›› 2016, Vol. 32 ›› Issue (1): 8-15.doi: 10.1007/s40242-016-5288-2

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Effect of Reaction Conditions on the Assembly, Structures and Fluorescent Sensing Behaviors of Cd(Ⅱ) Metal-organic Complexes

LE Mao, LUAN Jian, ZHAO Xunzhang, TANG Tang, CHEN Panwen, LIU Guocheng, LIN Hongyan

Department of Chemistry, Bohai University, Jinzhou 121013, P. R. China

Received:2015-07-20 Revised:2015-09-27 Online:2016-02-01 Published:2015-10-12
Contact: LIN Hongyan E-mail:linhongyan_2015@126.com
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21171025, 21471021, 21401010, 21501013).

Abstract

Abstract:

Three Cd(Ⅱ) metal-organic complexes, namely[Cd(phen)₂Cl₂](1),[Cd(phen)Cl₂](2) and[Cd(phen)(cam)]·H₂O(3)(phen=1,10-phenanthroline, H₂cam=camphoric acid), were hydrothermally synthesized using Cd²⁺, phen and H₂cam as raw materials under different conditions of pH values, reaction temperatures or reactant ratios. The prepared complexes were structurally characterized by means of single-crystal X-ray diffraction, and the results show that complex 1 is a 2D supramolecular complex, which consists of[Cd(phen)₂Cl₂] mononuclear subunits, while complex 2 shows a 1D chain structure, in which Cd(Ⅱ) ions are connected by chloride(Cl^-) bridges, with phen hanging on both sides of the chain. No cam anions have been observed in the structures of complexes 1 and 2. In complex 3, cam connects Cd(Ⅱ) ions to construct a 2D network, in which phen acts as terminal ligands. The adjacent 1D chains for complex 2 and the adjacent 2D layers for complex 3 are further linked by hydrogen bonding interactions or π-π intermolecular interactions to form 3D supramolecular networks, respectively. The effects of reaction conditions on the assembly and structures of the complexes have been discussed. The fluorescent and photocatalytic properties of complexes 1-3 and the fluorescent sensing behaviors of complexes 2 and 3 have also been investigated.

Key words: Cd(Ⅱ) complex, 1,10-Phenanthroline, Camphanic acid, Fluorescent sensing behavior, Photocatalytic property

LE Mao, LUAN Jian, ZHAO Xunzhang, TANG Tang, CHEN Panwen, LIU Guocheng, LIN Hongyan. Effect of Reaction Conditions on the Assembly, Structures and Fluorescent Sensing Behaviors of Cd(Ⅱ) Metal-organic Complexes[J]. Chemical Research in Chinese Universities, 2016, 32(1): 8-15.

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Effect of Reaction Conditions on the Assembly, Structures and Fluorescent Sensing Behaviors of Cd(Ⅱ) Metal-organic Complexes

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