Synthesis and Electrochemical Properties of Highly Crystallized CuV2O6 Nanowires

doi:10.1007/s40242-015-5136-9

Chemical Research in Chinese Universities ›› 2015, Vol. 31 ›› Issue (5): 708-711.doi: 10.1007/s40242-015-5136-9

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Synthesis and Electrochemical Properties of Highly Crystallized CuV₂O₆ Nanowires

HU Fang^1,2, LI Malin², WEI Yingjin², DU Fei², CHEN Gang², WANG Chunzhong²

1. School of Materials Science and Engineering, Shenyang University of Technology, Shenyang 110870, P. R. China;
2. Key Laboratory of Advanced Batteries Physics and Technology, Ministry of Education, College of Physics, Jilin University, Changchun 130012, P. R. China

Received:2015-04-03 Revised:2015-06-12 Online:2015-10-01 Published:2015-10-10
Contact: WANG Chunzhong, E-mail: wcz@jlu.edu.cn E-mail:wcz@jlu.edu.cn
Supported by:
Supported by the National Basic Research Program of China(No.2015CB251103), the National Natural Science Foundation of China(No.51472104) and the Development Program of Science and Technology of Jilin Province, China(No.20140101093JC).

Abstract

Abstract:

CuV₂O₆ nanowires were prepared via a simple hydrothermal route using NH₄VO₃ and Cu(NO₃)₂ as starting materials. The structures and electrochemical properties of CuV₂O₆ nanowires were characterized by means of X-ray diffraction(XRD), scanning electron microscopy(SEM) and transmission electron microscopy(TEM). The results show that the CuV₂O₆ nanowires are about 100 nm in width and single crystalline grown along [001] direction. CuV₂O₆ nanowires delivered a high initial discharge capacity of 435 and 351 mA·h/g at current densities of 50 and 100 mA·h/g, respectively. The electrochemical kinetics of the CuV₂O₆ nanowires was also investigated by means of electrochemical impedance spectroscopy(EIS) and the poor rate performance was observed, which may be attributed to the low ion diffusion coefficient of the CuV₂O₆ nanowires.

Key words: CuV₂O₆, Nanowire, Electrochemical property

HU Fang, LI Malin, WEI Yingjin, DU Fei, CHEN Gang, WANG Chunzhong. Synthesis and Electrochemical Properties of Highly Crystallized CuV₂O₆ Nanowires[J]. Chemical Research in Chinese Universities, 2015, 31(5): 708-711.

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Synthesis and Electrochemical Properties of Highly Crystallized CuV₂O₆ Nanowires

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