Transformation of Ethanol to Ethyl Acetate over Cu/SiO2 Catalysts Modified by ZrO2

doi:10.1007/s40242-013-3024-8

Chemical Research in Chinese Universities ›› 2013, Vol. 29 ›› Issue (5): 986-990.doi: 10.1007/s40242-013-3024-8

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Transformation of Ethanol to Ethyl Acetate over Cu/SiO₂ Catalysts Modified by ZrO₂

YU Xue¹, ZHU Wan-chun¹, GAO Shuang¹, CHEN Li-li¹, YUAN Hong-jing¹, LUO Jia-huan², WANG Zhen-lü¹, ZHANG Wen-xiang¹

1. Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Jilin University, Changchun 130021, P. R. China;
2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2013-01-14 Revised:2013-04-01 Online:2013-10-01 Published:2013-09-17
Contact: WANG Zhen-lü, ZHANG Wen-xiang E-mail:wzl@jlu.edu.cn;zhwenx@jlu.edu.cn
Supported by:
Supported by the Natural Science Foundation of Science and Technology Department of Jilin Province, China(No.20130101015JC), the Open Project Supported by State Key Laboratory of Inorganic Synthesis and Preparative Chemistry of Jilin University, China (No.2012-15), and the Innovation Project of Frontiers of Science and New Interdiscipline of Jilin University, China.

Abstract

Abstract:

Direct transformation of ethanol to ethyl acetate was investigated on a series of Cu(ZrO₂)/SiO₂ catalysts. Inductively coupled plasma(ICP), surface area analysis, X-ray diffraction(XRD), H₂-temperature programmed reduction(H₂-TPR), X-ray photoelectron spectroscopy(XPS), NH₃-temperature programmed desorption(NH₃-TPD) and Fourier transform-infrared spectroscopy(FTIR) techniques were used to characterize the catalysts. The results reveal that ZrO₂ can improve the dispersion of copper species and increase the acidity of the Cu(ZrO₂)/SiO₂catalysts. The Cu⁰ is responsible for ethanol dehydrogenation to acetaldehyde, and both the Lewis acid and Brønsted acid sites were in favor of the selectivity to ethyl acetate. The synergistic effect of Cu⁰ and an appropriate amount of acidic sites played an important role in the production of ethyl acetate.

Key words: Ethyl acetate, Ethanol, Zirconium, Copper based catalyst, Acid site

YU Xue, ZHU Wan-chun, GAO Shuang, CHEN Li-li, YUAN Hong-jing, LUO Jia-huan, WANG Zhen-lü, ZHANG Wen-xiang. Transformation of Ethanol to Ethyl Acetate over Cu/SiO₂ Catalysts Modified by ZrO₂[J]. Chemical Research in Chinese Universities, 2013, 29(5): 986-990.

References

[1] Gaspar A. B., Esteves A. M. L., Mendes F. M. T., Barbosa F. G., Appel L. G., Appl. Catal. A, 2009, 363, 109
[2] Weinstein R. D., Ferens A. R., Orange R. J., Lemaire P., Carbon, 2011, 49, 701
[3] Inui K., Kurabayashi T., Sato S., Appl. Catal. A, 2002, 237, 53
[4] Inui K., Kurabayashi T., Sato S., J. Catal., 2002, 212, 207
[5] Inui K., Kurabayashi T., Sato S., Ichikawa N., J. Mol. Catal. A: Chem., 2004, 216, 147
[6] Colley S. W., Tabatabaei J., Waugh K. C., Wood M. A., J. Catal., 2005, 236, 21
[7] Sánchez A. B., Homs N., Fierro J. L. G., Piscina P. R. D. L., Catal. Today, 2005, 107/108, 431
[8] Wang L. X., Zhu W. C., Zheng D. F., Yu X., Cui J., Jia M., Zhang W. X., Wang Z. L., Reac. Kinet. Mech. Cat., 2010, 101, 365
[9] Zonetti P. C., Celnik J., Letichevsky S., Gaspar A. B., Appel L. G., J. Mol. Catal. A: Chem., 2011, 334, 29
[10] Zhang M., Li G., Jiang H., Zhang J., Catal. Lett., 2011, 141, 1104
[11] Guerreiro E. D., Gorriz O. F., Rivarola J. B., Arrúa L. A., Appl. Catal. A, 1997, 165, 259
[12] Zhu W. C., Wang L. X., Liu S. Y., Wang Z., React. Kinet. Catal. Lett., 2008, 93, 93
[13] Zhu X., Li X., Jia M., Liu G., Zhang W., Jiang D., Appl. Catal. A, 2005, 282, 155
[14] Su W. G., Wang S. G., Ying P. L., Feng Z. C., Li C., J. Catal., 2009, 268, 165
[15] Si Z. C., Weng D., Wu X. D., Li J., Li G., J. Catal. , 2010, 271, 43
[16] Guerrero S., Guzmán I., Aguila G., Araya P., Catal. Commun., 2009, 11, 38
[17] Turco M., Cammarano C., Bagnasco G., Moretti E., Storaro L., Talon A., Lenarda M., Appl. Catal. B, 2009, 91, 101
[18] Esposito S., Turco M., Bagnasco G., Cammarano C., Pernice P., Appl. Catal. A, 2011, 403, 128
[19] Ji D. H., Zhu W. C., Wang Z. L., Wang G., Catal. Commun., 2007, 8, 1891
[20] Wang L. C., Liu Q., Chen M., Liu Y. M., Cao Y., He, Fan K. N., J. Phys. Chem. C, 2007, 111, 16549
[21] Jones S. D., Neal L. M., Everett M. L., Hoflund G. B., Hagelin-Weaver H. E., Appl. Surf. Sci., 2010, 256, 7345
[22] Zhuang H. D., Bai S. F., Liu X. M., Yan Z. F., J. Fuel. Chem. Technol., 2010, 38, 462
[23] Chary K. V. R., Sagar G. V., Naresh D., Seela K. K., Sridhar B., J. Phys. Chem. B, 2005, 109, 9437
[24] Matter P. H., Ozkan U. S., J. Catal., 2005, 234, 463
[25] Agrell J., Birgersson H., Boutonnet M., Melián-Cabrera I., Navarro R. M., Fierro J. L. G., J. Catal., 2003, 219, 389
[26] Chen X. R., Ju Y. H., Mou C. Y., J. Phys. Chem. C, 2007, 111, 18731
[27] Turco M., Bagnasco G., Cammarano C., Senese P., Costantino U., Sisani M., Appl. Catal. B, 2007, 77, 46
[28] Zheng H. Y., Zhu Y. L., Huang L., Zeng Z. Y., Wan H. J., Li Y. W., Catal. Commun., 2008, 9, 342
[29] Chen L. F., Noreña L. E., Navarrete J., Wang J. A., Mater. Chem. Phys., 2006, 97, 236
[30] Zhang Y. Q., Wang S. J., Wang J. W., Lou L. L., Zhang C., Liu S. X., Solid State Sci., 2009, 11, 1412
[31] Jia A. Z., Li J., Zhang Y. Q., Song Y. J., Liu S. X., Mater. Sci. Eng. C, 2008, 28, 1217
[32] Salas P., Wang J. A., Armendariz H., Angeles Chavez C., Chen L. F., Mater. Chem. Phys., 2009, 114, 139
[33] Guo X. K., Xie P. P., Lin S. D., J. Fuel. Chem. Technol., 2008, 36, 732
[34] Chang F. W., Kuo W. Y., Lee K. C., Appl. Catal. A, 2003, 246, 253
[35] Tada M., Bal R., Namba S., Iwasawa Y., Appl. Catal. A, 2006, 307, 78
[36] Jadhav S. V., Jinka K. M., Bajaj H. C., Appl. Catal. A, 2010, 390, 158
[37] Zhao T. S., Takemoto T., Tsubaki N., Catal. Commun., 2006, 7, 647
[38] He D., Ding Y., Luo H., Li C., J. Mol. Catal. A: Chem., 2004, 208, 267

Transformation of Ethanol to Ethyl Acetate over Cu/SiO₂ Catalysts Modified by ZrO₂

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